methyl 2-O-benzyl-6-O-tert-butyldiphenylsilyl-3-O-(6-O-tert-butyldiphenylsilyl-α-D-mannopyranosyl)-α-D-mannopyranoside

Base Information

Chemical Name:methyl 2-O-benzyl-6-O-tert-butyldiphenylsilyl-3-O-(6-O-tert-butyldiphenylsilyl-α-D-mannopyranosyl)-α-D-mannopyranoside
CAS No.:114284-16-1
Molecular Formula:C₅₂H₆₆O₁₁Si₂
Molecular Weight:923.26
Hs Code.:

Synonyms:methyl 2-O-benzyl-6-O-tert-butyldiphenylsilyl-3-O-(6-O-tert-butyldiphenylsilyl-α-D-mannopyranosyl)-α-D-mannopyranoside

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Chemical Property of methyl 2-O-benzyl-6-O-tert-butyldiphenylsilyl-3-O-(6-O-tert-butyldiphenylsilyl-α-D-mannopyranosyl)-α-D-mannopyranoside

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Technology Process of methyl 2-O-benzyl-6-O-tert-butyldiphenylsilyl-3-O-(6-O-tert-butyldiphenylsilyl-α-D-mannopyranosyl)-α-D-mannopyranoside

There total 5 articles about methyl 2-O-benzyl-6-O-tert-butyldiphenylsilyl-3-O-(6-O-tert-butyldiphenylsilyl-α-D-mannopyranosyl)-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.4%

: 114284-14-9
methyl 2-O-benzyl-3-O-α-D-mannopyranosyl-α-D-mannopyranoside

: 58479-61-1
tert-butylchlorodiphenylsilane

: 114284-16-1
methyl 2-O-benzyl-6-O-tert-butyldiphenylsilyl-3-O-(6-O-tert-butyldiphenylsilyl-α-D-mannopyranosyl)-α-D-mannopyranoside

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 0 ℃; for 1h;
DOI:10.1016/0008-6215(87)80098-8

Reference yield:

: 15038-71-8,15384-58-4,23392-29-2,40653-23-4,57539-07-8,76375-66-1,81872-62-0,86363-45-3,90639-38-6,108739-91-9,116002-34-7,130192-76-6,131433-04-0,141115-75-5,78185-83-8
methyl 2-O-benzyl-(R)-4,6-O-benzylidene-α-D-mannopyranoside

: 114284-16-1
methyl 2-O-benzyl-6-O-tert-butyldiphenylsilyl-3-O-(6-O-tert-butyldiphenylsilyl-α-D-mannopyranosyl)-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 1) Hg(CN)2, molecular sieves / 1) nitromethane, reflux, 3 h; 2) nitromethane, 40-45 deg C, 3 h

2: 60 percent / sodium methoxide / methanol / 4 h / Ambient temperature

3: 92 percent / acetic acid / H₂O / 2 h / 90 °C

4: 74.4 percent / imidazole / dimethylformamide / 1 h / 0 °C

With 1H-imidazole; molecular sieve; sodium methylate; mercury(II) cyanide; acetic acid; In methanol; water; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(87)80098-8

Reference yield:

: 114284-13-8,136657-64-2
methyl 2-O-benzyl-4,6-O-benzylidene-3-O-α-D-mannopyranosyl-α-D-mannopyranoside

: 114284-16-1
methyl 2-O-benzyl-6-O-tert-butyldiphenylsilyl-3-O-(6-O-tert-butyldiphenylsilyl-α-D-mannopyranosyl)-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / acetic acid / H₂O / 2 h / 90 °C

2: 74.4 percent / imidazole / dimethylformamide / 1 h / 0 °C

With 1H-imidazole; acetic acid; In water; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(87)80098-8