(+)-(S_S)-S-(2-E-hexenyloxycarbonylmethyl)-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine

Base Information

• Chemical Name: (+)-(S_S)-S-(2-E-hexenyloxycarbonylmethyl)-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine
• CAS No.: 864443-82-3
• Molecular Formula: C₂₉H₄₁NO₅S₂
• Molecular Weight: 547.78

Synonyms:(+)-(S_S)-S-(2-E-hexenyloxycarbonylmethyl)-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine

Chemical Property of (+)-(S_S)-S-(2-E-hexenyloxycarbonylmethyl)-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+)-(S_S)-S-(2-E-hexenyloxycarbonylmethyl)-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine

There total 2 articles about (+)-(S_S)-S-(2-E-hexenyloxycarbonylmethyl)-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

(+)-(SS)-S-carboxymethyl-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine (864443-80-1) + (E)-2-Hexen-1-ol (928-95-0) → (+)-(SS)-S-(2-E-hexenyloxycarbonylmethyl)-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine (864443-82-3)

Guidance literature:

With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 0 - 20 ℃; for 16h;

DOI:10.1021/jo050747d

Reference yield:

(+)-(SS)-S-methyl-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine → (+)-(SS)-S-(2-E-hexenyloxycarbonylmethyl)-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine (864443-82-3)

Guidance literature:

Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

1.2: 80 percent / tetrahydrofuran; hexane / 0.5 h / -78 °C

2.1: 72 percent / 1-(dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride / CH₂Cl₂ / 16 h / 0 - 20 °C

With n-butyllithium; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In tetrahydrofuran; hexane; dichloromethane;

DOI:10.1021/jo050747d

Reference yield:

(+)-(SS)-S-(2-E-hexenyloxycarbonylmethyl)-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine (864443-82-3) → (SS,S)-S-(2-propylbut-3-enyl)-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine + (SS,R)-S-(2-propylbut-3-enyl)-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine

Guidance literature:

With N,O-bis-(trimethylsilyl)-acetamide; potassium acetate; In toluene; for 6h; Title compound not separated from byproducts; Heating;

DOI:10.1021/jo050747d

upstream raw materials:

(+)-(S_S)-S-carboxymethyl-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine

(E)-2-Hexen-1-ol

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 864443-82-3 (+)-(S_S)-S-(2-E-hexenyloxycarbonylmethyl)-S-phenyl-N-(2,4,6-triisopropylphenylsulfonyl)sulfoximine

Send

Send

Metric Ton KG G Pound L ML

Send

Send