1,4-dimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene

Base Information

• Chemical Name: 1,4-dimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene
• CAS No.: 210817-42-8
• Molecular Formula: C₂₂H₂₈O₁₁
• Molecular Weight: 468.458
• Mol file: 210817-42-8.mol

Synonyms:1,4-dimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene

Chemical Property of 1,4-dimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,4-dimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene

There total 2 articles about 1,4-dimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

1,4-dimethoxybezene (150-78-7) + β-D-glucose pentaacetate (604-69-3) → 1,4-dimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene (210817-42-8)

Guidance literature:

With silver trifluoroacetate; tin(IV) chloride; In dichloromethane; at 25 ℃; for 5h;

DOI:10.1016/j.tetlet.2005.07.125

Reference yield: 52.0%

D-glucose pentaacetate (83-87-4,604-68-2,604-69-3,2152-77-4,4026-35-1,4163-59-1,4163-60-4,4163-61-5,4163-65-9,4257-94-7,4257-96-9,16299-15-3,19186-39-1,19189-55-0,25878-60-8,25941-03-1,32445-48-0,32445-49-1,32445-53-7,32445-54-8,34685-58-0,34685-59-1,43168-42-9,43168-44-1,43169-22-8,43169-25-1,66966-07-2,70749-17-6,80184-01-6,93221-01-3,93221-02-4,99630-88-3,109215-53-4,115792-70-6,115792-73-9,139894-92-1,139973-25-4,144071-49-8,147648-81-5) + 1,4-dimethoxybezene (150-78-7) → 1,4-dimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene (210817-42-8)

Guidance literature:

With silver trifluoromethanesulfonate; tin(IV) chloride; In dichloromethane; at 0 ℃; for 2h;

DOI:10.1080/07328309908544002

Reference yield: 100.0%

1,4-dimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene (210817-42-8) → 2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-1,4-benzoquinone (862201-11-4)

Guidance literature:

With ammonium cerium(IV) nitrate; In water; acetonitrile;

DOI:10.1016/j.tetlet.2005.07.125

upstream raw materials:

D-glucose pentaacetate

1,4-dimethoxybezene

β-D-glucose pentaacetate

Downstream raw materials:

2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-1,4-benzoquinone

2-(β-D-glucopyranosyl)hydroquinone

2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)hydroquinone

6-chloro-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-1,4-dimethoxybenzene