4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzoic acid chloride

Base Information

Chemical Name:4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzoic acid chloride
CAS No.:138785-39-4
Molecular Formula:C₂₉H₅₀ClIO₈Si₂
Molecular Weight:745.24
Hs Code.:

Synonyms:4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzoic acid chloride

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Chemical Property of 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzoic acid chloride

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Technology Process of 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzoic acid chloride

There total 29 articles about 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzoic acid chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 138785-39-4
4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzoic acid chloride

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / pyridine / CH₂Cl₂

2: 77 percent / DIBAH / CH₂Cl₂

3: 1.) NaClO₂, NaHPO₄, 2.) (COCl₂)2 / 1.) H₂O, t-BuOH

With pyridine; sodium chlorite; (COCl₂)2; camphor-10-sulfonic acid; diisobutylaluminium hydride; In dichloromethane;
DOI:10.1021/jo951560x

Reference yield:

: 168567-07-5
4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzaldehyde

: 138785-39-4
4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzoic acid chloride

Guidance literature:: With sodium chlorite; (COCl₂)2; camphor-10-sulfonic acid; Multistep reaction; 1.) H₂O, t-BuOH;
DOI:10.1021/jo951560x

Reference yield:

: 168567-08-6
4-<(6-deoxy-4-O-<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzonitrile

: 138785-39-4
4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzoic acid chloride

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / pyridine / CH₂Cl₂

2: 77 percent / DIBAH / CH₂Cl₂

3: 1.) NaClO₂, NaHPO₄, 2.) (COCl₂)2 / 1.) H₂O, t-BuOH

With pyridine; sodium chlorite; (COCl₂)2; camphor-10-sulfonic acid; diisobutylaluminium hydride; In dichloromethane;
DOI:10.1021/jo951560x