dihydrido(η5-pentamethylcyclopentadienyl)(5-(diphenylphosphino)-25,26,27,28-tetra-n-propoxycalix[4]arene)rhodium(III)

Base Information

• Chemical Name: dihydrido(η5-pentamethylcyclopentadienyl)(5-(diphenylphosphino)-25,26,27,28-tetra-n-propoxycalix[4]arene)rhodium(III)
• CAS No.: 287944-37-0
• Molecular Formula: C₆₂H₇₄O₄PRh
• Molecular Weight: 1017.15
• Mol file: 287944-37-0.mol

Synonyms:dihydrido(η5-pentamethylcyclopentadienyl)(5-(diphenylphosphino)-25,26,27,28-tetra-n-propoxycalix[4]arene)rhodium(III)

Chemical Property of dihydrido(η5-pentamethylcyclopentadienyl)(5-(diphenylphosphino)-25,26,27,28-tetra-n-propoxycalix[4]arene)rhodium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of dihydrido(η5-pentamethylcyclopentadienyl)(5-(diphenylphosphino)-25,26,27,28-tetra-n-propoxycalix[4]arene)rhodium(III)

There total 1 articles about dihydrido(η5-pentamethylcyclopentadienyl)(5-(diphenylphosphino)-25,26,27,28-tetra-n-propoxycalix[4]arene)rhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

sodium tetrahydroborate (16940-66-2) + dichloro(η5-pentamethylcyclopentadienyl)(5-(diphenylphosphino)-25,26,27,28-tetra-n-propoxycalix[4]arene)rhodium(III) (287944-36-9) → dihydrido(η5-pentamethylcyclopentadienyl)(5-(diphenylphosphino)-25,26,27,28-tetra-n-propoxycalix[4]arene)rhodium(III) (287944-37-0)

Guidance literature:

In ethanol; (N2, darkness); refluxing a soln. of rhodium complex in ethanol for minutes, addn. of a suspn. of NaBH4 in ethanol, stirring for 1 h; evapn., dissolving in C6H6, filtration, evapn.; elem. anal.;

DOI:10.1021/om000433a

upstream raw materials:

sodium tetrahydroborate

dichloro(η5-pentamethylcyclopentadienyl)(5-(diphenylphosphino)-25,26,27,28-tetra-n-propoxycalix[4]arene)rhodium(III)