dimethyl 1,8-diaza-4,5-diisobutoxy-9-[benzylmercapto]-2,7-anthracenedicarboxylate

Base Information

• Chemical Name: dimethyl 1,8-diaza-4,5-diisobutoxy-9-[benzylmercapto]-2,7-anthracenedicarboxylate
• CAS No.: 1567373-78-7
• Molecular Formula: C₃₁H₃₄N₂O₆S
• Molecular Weight: 562.687
• Mol file: 1567373-78-7.mol

Synonyms:dimethyl 1,8-diaza-4,5-diisobutoxy-9-[benzylmercapto]-2,7-anthracenedicarboxylate

Chemical Property of dimethyl 1,8-diaza-4,5-diisobutoxy-9-[benzylmercapto]-2,7-anthracenedicarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dimethyl 1,8-diaza-4,5-diisobutoxy-9-[benzylmercapto]-2,7-anthracenedicarboxylate

There total 2 articles about dimethyl 1,8-diaza-4,5-diisobutoxy-9-[benzylmercapto]-2,7-anthracenedicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

dimethyl 1,8-diaza-4,5-diisobutoxy-9-chloro-2,7-anthracenedicarboxylate (1567373-77-6) + phenylmethanethiol (100-53-8) → dimethyl 1,8-diaza-4,5-diisobutoxy-9-[benzylmercapto]-2,7-anthracenedicarboxylate (1567373-78-7)

Guidance literature:

With caesium carbonate; In toluene; at 20 ℃;

DOI:10.1021/jo402852m

Reference yield:

dimethyl 10-chloro-4,6-dioxo-1,4,6,9-tetrahydropyrido[3,2-g]quinoline-2,8-dicarboxylate (49635-49-6) → dimethyl 1,8-diaza-4,5-diisobutoxy-9-[benzylmercapto]-2,7-anthracenedicarboxylate (1567373-78-7)

Guidance literature:

Multi-step reaction with 2 steps

1: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran / 0 - 20 °C

2: caesium carbonate / toluene / 20 °C

With di-isopropyl azodicarboxylate; caesium carbonate; triphenylphosphine; In tetrahydrofuran; toluene;

DOI:10.1021/jo402852m

upstream raw materials:

dimethyl 1,8-diaza-4,5-diisobutoxy-9-chloro-2,7-anthracenedicarboxylate

phenylmethanethiol

dimethyl 10-chloro-4,6-dioxo-1,4,6,9-tetrahydropyrido[3,2-g]quinoline-2,8-dicarboxylate