cis-bis(trimethylphosphine)tetracarbonylmolybdenum

Base Information

• Chemical Name: cis-bis(trimethylphosphine)tetracarbonylmolybdenum
• CAS No.: 16027-45-5
• Molecular Formula: C₁₀H₁₈MoO₄P₂
• Molecular Weight: 360.138
• Mol file: 16027-45-5.mol

Synonyms:cis-bis(trimethylphosphine)tetracarbonylmolybdenum

Chemical Property of cis-bis(trimethylphosphine)tetracarbonylmolybdenum

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of cis-bis(trimethylphosphine)tetracarbonylmolybdenum

There total 4 articles about cis-bis(trimethylphosphine)tetracarbonylmolybdenum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) (12146-37-1,124717-04-0) + trimethylphosphane (594-09-2) → cis-bis(trimethylphosphine)tetracarbonylmolybdenum (16027-45-5) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0)

Guidance literature:

In tetrahydrofuran; reaction in a calorimeter under argon;

Reference yield:

bis[dimethylbis(trimethylphosphine)molybdenum](Mo-Mo) → (trimethylphosphine)pentacarbonylmolybdenum (16917-96-7) + Mo(CO)4(P(CH3)3)2 (16027-45-5,16917-98-9,30513-03-2) + (PMe3)3Mo(CO)3 (16918-01-7,19195-94-9,30513-05-4) + molybdenum hexacarbonyl (13939-06-5,199620-15-0)

Guidance literature:

With carbon monoxide; In benzene; byproducts: acetone; under 18 atm., at room temp.; followed by NMR;

DOI:10.1021/ja00403a069

Reference yield:

[(κ2-(CH3C(SiMe2PPPh2)3)Mo(CO)4] + trimethylphosphane (594-09-2) → trans-Mo(CO)4(PMe3)2 (30513-03-2) + cis-bis(trimethylphosphine)tetracarbonylmolybdenum (16027-45-5) + [(κ3-(CH3C(SiMe2PPPh2)3)Mo(CO)3] (905965-75-5) + [(κ2-(CH3C(SiMe2PPPh2)3)Mo(PMe3)(CO)3] (905965-74-4)

Guidance literature:

In ⁽²⁾H₈-toluene; byproducts: CH3C(SiMe2PPPh2)3, CO; (N2); Schlenk technique; soln. of Mo complex and PMe3 in toluene-d8 in sealed NMR tube was heated at 85°C for 12 h; NMR monitoring; not isolated;

DOI:10.1039/b516127d

upstream raw materials:

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum⁽⁰⁾

trimethylphosphane

cis-tetracarbonylbis(piperidine)molybdenum

3,4-dimethyl-1-phenylphosphole