tetraphenylarsonium (pentacarbonylmanganese)tetracarbonylnitrosylvanadate

Base Information

• Chemical Name: tetraphenylarsonium (pentacarbonylmanganese)tetracarbonylnitrosylvanadate
• CAS No.: 84911-12-6
• Molecular Formula: C₉MnNO₁₀V*C₂₄H₂₀As
• Molecular Weight: 771.324
• Mol file: 84911-12-6.mol

Synonyms:tetraphenylarsonium (pentacarbonylmanganese)tetracarbonylnitrosylvanadate

Chemical Property of tetraphenylarsonium (pentacarbonylmanganese)tetracarbonylnitrosylvanadate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tetraphenylarsonium (pentacarbonylmanganese)tetracarbonylnitrosylvanadate

There total 1 articles about tetraphenylarsonium (pentacarbonylmanganese)tetracarbonylnitrosylvanadate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

[(C6H5)4As](1+)*[Mn(CO)5](1-)=[(C6H5)4As][Mn(CO)5] (67047-44-3) + tetraphenyl arsenium hexacarbonyl vanadate (-I) (57304-95-7) + nitrosonium tetrafluoroborate → tetraphenylarsonium (pentacarbonylmanganese)tetracarbonylnitrosylvanadate (84911-12-6) + tetraphenylarsonium tetrafluoroborate

Guidance literature:

In dichloromethane; under N2, soln. of V-complex was transferred to (NO)(BF4) at -50°C, stirred for 1.5 h at -40°C, soln. of Mn-complex was added at -40°C, stirred mixture was allowed to slowly warm; CH2Cl2 was removed at -5 to -4°C, dissolved (cold (-30 to -40°C) CH2Cl2, filtered, heptane added, cooled to -78°C, (Ph4As)(BF4) separated by filtration, heptane added, filtered, washed (heptane),filtrate concd.; elem. anal.;

DOI:10.1021/ja00346a033

upstream raw materials:

[(C₆H₅)4As]⁽¹⁺⁾*[Mn(CO)5]^(1-)=[(C₆H₅)4As][Mn(CO)5]

tetraphenyl arsenium hexacarbonyl vanadate (-I)