phenylmethyl 4,6-dideoxy-4-<<<2,6-dideoxy-4-S-(2,4,6-trimethylbenzoyl)-4-thio-β-D-ribo-hexopyranosyl>oxy>amino>-2-O-(phenylmethyl)-α-D-glucopyranoside

Base Information

Chemical Name:phenylmethyl 4,6-dideoxy-4-<<<2,6-dideoxy-4-S-(2,4,6-trimethylbenzoyl)-4-thio-β-D-ribo-hexopyranosyl>oxy>amino>-2-O-(phenylmethyl)-α-D-glucopyranoside
CAS No.:126925-58-4
Molecular Formula:C₃₆H₄₅NO₈S
Molecular Weight:651.821
Hs Code.:

phenylmethyl 4,6-dideoxy-4-<<<2,6-dideoxy-4-S-(2,4,6-trimethylbenzoyl)-4-thio-β-D-ribo-hexopyranosyl>oxy>amino>-2-O-(phenylmethyl)-α-D-glucopyranoside

Synonyms:phenylmethyl 4,6-dideoxy-4-<<<2,6-dideoxy-4-S-(2,4,6-trimethylbenzoyl)-4-thio-β-D-ribo-hexopyranosyl>oxy>amino>-2-O-(phenylmethyl)-α-D-glucopyranoside

Suppliers and Price of phenylmethyl 4,6-dideoxy-4-<<<2,6-dideoxy-4-S-(2,4,6-trimethylbenzoyl)-4-thio-β-D-ribo-hexopyranosyl>oxy>amino>-2-O-(phenylmethyl)-α-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenylmethyl 4,6-dideoxy-4-<<<2,6-dideoxy-4-S-(2,4,6-trimethylbenzoyl)-4-thio-β-D-ribo-hexopyranosyl>oxy>amino>-2-O-(phenylmethyl)-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenylmethyl 4,6-dideoxy-4-<<<2,6-dideoxy-4-S-(2,4,6-trimethylbenzoyl)-4-thio-β-D-ribo-hexopyranosyl>oxy>amino>-2-O-(phenylmethyl)-α-D-glucopyranoside

There total 33 articles about phenylmethyl 4,6-dideoxy-4-<<<2,6-dideoxy-4-S-(2,4,6-trimethylbenzoyl)-4-thio-β-D-ribo-hexopyranosyl>oxy>amino>-2-O-(phenylmethyl)-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 126900-95-6
2,4,6-Trimethyl-thiobenzoic acid S-{(2R,3S,4S,6S)-6-[(2R,4S,5R,6S)-5,6-bis-benzyloxy-4-hydroxy-2-methyl-dihydro-pyran-(3E)-ylideneaminooxy]-4-hydroxy-2-methyl-tetrahydro-pyran-3-yl} ester

: 126925-58-4
phenylmethyl 4,6-dideoxy-4-<<<2,6-dideoxy-4-S-(2,4,6-trimethylbenzoyl)-4-thio-β-D-ribo-hexopyranosyl>oxy>amino>-2-O-(phenylmethyl)-α-D-glucopyranoside

Guidance literature:: With borane-ammonia complex; pyridinium p-toluenesulfonate; at 25 ℃; for 4h;

Reference yield: 81.0%

: phenylmethyl 6-deoxy-2-O-(phenylmethyl)-α-D-xylo-hexopyranosid-4-ulose O-<2,6-dideoxy-4-S-(2,4,6-trimethylbenzoyl)-4-thio-β-D-ribo-hexopyranosyl>oxime

: 126925-58-4
phenylmethyl 4,6-dideoxy-4-<<<2,6-dideoxy-4-S-(2,4,6-trimethylbenzoyl)-4-thio-β-D-ribo-hexopyranosyl>oxy>amino>-2-O-(phenylmethyl)-α-D-glucopyranoside

Guidance literature:: With borane-ammonia complex; pyridinium p-toluenesulfonate; In tetrahydrofuran; at 25 ℃;

Reference yield:

: 126925-59-5
(2R)-trans-4-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-3,6-dihydro-6-methyl-3-oxo-2H-pyran-2-yl 3-chlorobenzoate

: 126925-58-4
phenylmethyl 4,6-dideoxy-4-<<<2,6-dideoxy-4-S-(2,4,6-trimethylbenzoyl)-4-thio-β-D-ribo-hexopyranosyl>oxy>amino>-2-O-(phenylmethyl)-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 13 steps

1: Zn(BH₄)2, NH₄Cl / diethyl ether / 0.33 h / 0 °C

2: PPh₃, diisopropyl azodicarboxylate (DIAD) / tetrahydrofuran / 0.5 h

3: 100 percent / 55percent aq. NH₂NH₂*H₂O / methanol / 0.25 h / 25 °C

4: PPTS / benzene / 3 h / 25 °C

5: 99 percent / 2,6-lutidine / CH₂Cl₂ / 0.42 h / -25 - 0 °C

6: 90 percent / DIBAL / CH₂Cl₂ / 0.75 h / -78 °C

7: acetonitrile / 16 h / 25 °C

8: DIBAL / CH₂Cl₂ / 2 h / -78 °C

9: Et₃N, DMAP / CH₂Cl₂ / 12 h / 25 °C

10: TBAF, aq. AcOH / tetrahydrofuran / 0.25 h / 0 °C

11: K-Selectride / 1,2-dimethoxy-ethane; tetrahydrofuran / 1 h / -70 - -30 °C

12: 98 percent / TBAF / tetrahydrofuran / 0.5 h / 0 °C

13: 81 percent / BH₃*NH₃, PPTS / tetrahydrofuran / 25 °C

With 2,6-dimethylpyridine; dmap; borane-ammonia complex; zinc(II) tetrahydroborate; di-isopropyl azodicarboxylate; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; potassium tri-sec-butyl-borohydride; ammonium chloride; hydrazine hydrate; acetic acid; triethylamine; triphenylphosphine; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; diethyl ether; dichloromethane; acetonitrile; benzene;