4-((4'-((10-(acryloyloxy)decyl)oxy)-2,5-dimethoxy-[1,1'-biphenyl]-4-yl)ethynyl)benzoic acid

Base Information

Chemical Name:4-((4'-((10-(acryloyloxy)decyl)oxy)-2,5-dimethoxy-[1,1'-biphenyl]-4-yl)ethynyl)benzoic acid
CAS No.:1383422-01-2
Molecular Formula:C₃₆H₄₀O₇
Molecular Weight:584.709
Hs Code.:

Synonyms:4-((4'-((10-(acryloyloxy)decyl)oxy)-2,5-dimethoxy-[1,1'-biphenyl]-4-yl)ethynyl)benzoic acid

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Chemical Property of 4-((4'-((10-(acryloyloxy)decyl)oxy)-2,5-dimethoxy-[1,1'-biphenyl]-4-yl)ethynyl)benzoic acid

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Technology Process of 4-((4'-((10-(acryloyloxy)decyl)oxy)-2,5-dimethoxy-[1,1'-biphenyl]-4-yl)ethynyl)benzoic acid

There total 6 articles about 4-((4'-((10-(acryloyloxy)decyl)oxy)-2,5-dimethoxy-[1,1'-biphenyl]-4-yl)ethynyl)benzoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 1383422-00-1
4-((4'-((10-hydroxydecyl)oxy)-2,5-dimethoxy-[1,1'-biphenyl]-4-yl)ethynyl)benzoic acid

: 814-68-6,25189-84-8
acryloyl chloride

: 1383422-01-2
4-((4'-((10-(acryloyloxy)decyl)oxy)-2,5-dimethoxy-[1,1'-biphenyl]-4-yl)ethynyl)benzoic acid

Guidance literature:: With 2,6-di-tert-butyl-4-methyl-phenol; N,N-dimethyl-aniline; In 1,4-dioxane; at 50 ℃; for 4h; Inert atmosphere;
DOI:10.1039/c2jm31367g

Reference yield:

: 1383421-96-2
2-((4'-bromo-2',5'-dimethoxy-[1,1'-biphenyl]-4-yl)oxy)tetrahydro-2H-pyran

: 1383422-01-2
4-((4'-((10-(acryloyloxy)decyl)oxy)-2,5-dimethoxy-[1,1'-biphenyl]-4-yl)ethynyl)benzoic acid

Guidance literature:: Multi-step reaction with 5 steps

1.1: copper(l) iodide; triethylamine; triphenylphosphine / tetrahydrofuran / 0.08 h / Inert atmosphere

1.2: 70 °C / Inert atmosphere

2.1: toluene-4-sulfonic acid / methanol; dichloromethane / 20 °C

3.1: potassium carbonate; potassium iodide / acetone / 48 h / Reflux; Inert atmosphere

4.1: water; potassium hydroxide / tetrahydrofuran; ethanol / Reflux

5.1: 2,6-di-tert-butyl-4-methyl-phenol; N,N-dimethyl-aniline / 1,4-dioxane / 4 h / 50 °C / Inert atmosphere

With copper(l) iodide; 2,6-di-tert-butyl-4-methyl-phenol; water; potassium carbonate; toluene-4-sulfonic acid; N,N-dimethyl-aniline; triethylamine; triphenylphosphine; potassium iodide; potassium hydroxide; In tetrahydrofuran; 1,4-dioxane; methanol; ethanol; dichloromethane; acetone; 1.1: Sonogashira coupling / 1.2: Sonogashira coupling;
DOI:10.1039/c2jm31367g

Reference yield:

: 36603-49-3
4-(tetrahydropyran-2'-yloxy)-1-bromobenzene

: 1383422-01-2
4-((4'-((10-(acryloyloxy)decyl)oxy)-2,5-dimethoxy-[1,1'-biphenyl]-4-yl)ethynyl)benzoic acid

Guidance literature:: Multi-step reaction with 7 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1.5 h / -78 °C / Inert atmosphere

1.2: -78 - 20 °C / Inert atmosphere

2.1: potassium carbonate / ethanol; toluene / 0.17 h / 20 °C / Inert atmosphere

2.2: 6 h / 90 °C / Inert atmosphere

3.1: copper(l) iodide; triethylamine; triphenylphosphine / tetrahydrofuran / 0.08 h / Inert atmosphere

3.2: 70 °C / Inert atmosphere

4.1: toluene-4-sulfonic acid / methanol; dichloromethane / 20 °C

5.1: potassium carbonate; potassium iodide / acetone / 48 h / Reflux; Inert atmosphere

6.1: water; potassium hydroxide / tetrahydrofuran; ethanol / Reflux

7.1: 2,6-di-tert-butyl-4-methyl-phenol; N,N-dimethyl-aniline / 1,4-dioxane / 4 h / 50 °C / Inert atmosphere

With copper(l) iodide; n-butyllithium; 2,6-di-tert-butyl-4-methyl-phenol; water; potassium carbonate; toluene-4-sulfonic acid; N,N-dimethyl-aniline; triethylamine; triphenylphosphine; potassium iodide; potassium hydroxide; In tetrahydrofuran; 1,4-dioxane; methanol; ethanol; hexane; dichloromethane; acetone; toluene; 2.1: Suzuki coupling / 2.2: Suzuki coupling / 3.1: Sonogashira coupling / 3.2: Sonogashira coupling;
DOI:10.1039/c2jm31367g