2-diazo-malonic acid 2-[(allyl-benzyl-amino)-methyl]-4-nitro-phenyl ester ethyl ester

Base Information

Chemical Name:2-diazo-malonic acid 2-[(allyl-benzyl-amino)-methyl]-4-nitro-phenyl ester ethyl ester
CAS No.:612500-25-1
Molecular Formula:C₂₂H₂₂N₄O₆
Molecular Weight:438.44
Hs Code.:

Synonyms:2-diazo-malonic acid 2-[(allyl-benzyl-amino)-methyl]-4-nitro-phenyl ester ethyl ester

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Chemical Property of 2-diazo-malonic acid 2-[(allyl-benzyl-amino)-methyl]-4-nitro-phenyl ester ethyl ester

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Technology Process of 2-diazo-malonic acid 2-[(allyl-benzyl-amino)-methyl]-4-nitro-phenyl ester ethyl ester

There total 3 articles about 2-diazo-malonic acid 2-[(allyl-benzyl-amino)-methyl]-4-nitro-phenyl ester ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 57072-87-4
chlorocarbonyl-diazo-acetic acid ethyl ester

: 612500-21-7
2-[(allyl-benzyl-amino)-methyl]-4-nitro-phenol

: 612500-25-1
2-diazo-malonic acid 2-[(allyl-benzyl-amino)-methyl]-4-nitro-phenyl ester ethyl ester

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 20 ℃;
DOI:10.1016/S0040-4039(03)01778-7

Reference yield:

: 97-51-8
5-Nitrosalicylaldehyde

: 612500-25-1
2-diazo-malonic acid 2-[(allyl-benzyl-amino)-methyl]-4-nitro-phenyl ester ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / NaBH(OAc)3 / 1,2-dichloro-ethane / 20 °C

2: 69 percent / K₂CO₃ / acetonitrile

3: 65 percent / 2,6-lutidine / CH₂Cl₂ / 20 °C

With 2,6-dimethylpyridine; sodium tris(acetoxy)borohydride; potassium carbonate; In dichloromethane; 1,2-dichloro-ethane; acetonitrile;
DOI:10.1016/S0040-4039(03)01778-7

Reference yield:

: 100-46-9
benzylamine

: 612500-25-1
2-diazo-malonic acid 2-[(allyl-benzyl-amino)-methyl]-4-nitro-phenyl ester ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / NaBH(OAc)3 / 1,2-dichloro-ethane / 20 °C

2: 69 percent / K₂CO₃ / acetonitrile

3: 65 percent / 2,6-lutidine / CH₂Cl₂ / 20 °C

With 2,6-dimethylpyridine; sodium tris(acetoxy)borohydride; potassium carbonate; In dichloromethane; 1,2-dichloro-ethane; acetonitrile;
DOI:10.1016/S0040-4039(03)01778-7