Technology Process of tricarbonyl(η5-2-ethyl-5-methylcyclopenta[b]thienyl)manganese(I)
There total 1 articles about tricarbonyl(η5-2-ethyl-5-methylcyclopenta[b]thienyl)manganese(I) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
n-BuLi;
In
diethyl ether; hexane;
(Ar); Schlenk glassware; soln. of n-BuLi in hexane was added to soln. ofisomer mixt. of ligand in ether at room temp.; mixt. was stirred for 12 h; cooled to -40°C; Mn complex was added; soln. was stirred at - 40°C for 1 h; solvent evapd. (vac.); hexane added; refluxed for 3 h; concd.; chromd. (silica gel, hexane); evapd. (vac.); dissolved in CH2Cl2; CF3CO2H added; stirred for 15 min; filtered; filtrate evapd. (vac.); elem. anal.;
DOI:10.1023/B:RUGC.0000025177.78155.a1
