(11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1-3)-O-[α-L-rhamnopyranosyl-(1-4)]-O-α-L-rhamnopyranosyl-(1-4)-O-α-L-rhamnopyranosyl-(1-2)-β-D-glucopyranoside

Base Information

• Chemical Name: (11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1-3)-O-[α-L-rhamnopyranosyl-(1-4)]-O-α-L-rhamnopyranosyl-(1-4)-O-α-L-rhamnopyranosyl-(1-2)-β-D-glucopyranoside
• CAS No.: 1137099-42-3
• Molecular Formula: C₄₆H₈₂O₂₄
• Molecular Weight: 1019.14
• Mol file: 1137099-42-3.mol

Synonyms:(11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1-3)-O-[α-L-rhamnopyranosyl-(1-4)]-O-α-L-rhamnopyranosyl-(1-4)-O-α-L-rhamnopyranosyl-(1-2)-β-D-glucopyranoside

Chemical Property of (11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1-3)-O-[α-L-rhamnopyranosyl-(1-4)]-O-α-L-rhamnopyranosyl-(1-4)-O-α-L-rhamnopyranosyl-(1-2)-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1-3)-O-[α-L-rhamnopyranosyl-(1-4)]-O-α-L-rhamnopyranosyl-(1-4)-O-α-L-rhamnopyranosyl-(1-2)-β-D-glucopyranoside

There total 9 articles about (11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1-3)-O-[α-L-rhamnopyranosyl-(1-4)]-O-α-L-rhamnopyranosyl-(1-4)-O-α-L-rhamnopyranosyl-(1-2)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cairicoside E (1467762-18-0) → (S)-2-Methylbutyric acid (1730-91-2) + 1-decanoic acid (334-48-5) + (11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1-3)-O-[α-L-rhamnopyranosyl-(1-4)]-O-α-L-rhamnopyranosyl-(1-4)-O-α-L-rhamnopyranosyl-(1-2)-β-D-glucopyranoside (1137099-42-3)

Guidance literature:

cairicoside E; With potassium hydroxide; at 90 ℃; for 2h;

With hydrogenchloride; In water; pH=4;

DOI:10.1016/j.phytochem.2013.07.006

Reference yield:

(11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1→3)-O-[3-O-(trans-cinnamoyl)-4-O-(2S-methylbutanoyl)-α-L-rhamnopyranosyl-(1→4)]-O-(2-O-n-decanoyl)-α-L-rhamnopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-O-β-D-glucopyranoside-(1,3''-lactone) (1467762-13-5) → (S)-2-Methylbutyric acid (1730-91-2) + 1-decanoic acid (334-48-5) + (E)-3-phenylacrylic acid (140-10-3) + (11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1-3)-O-[α-L-rhamnopyranosyl-(1-4)]-O-α-L-rhamnopyranosyl-(1-4)-O-α-L-rhamnopyranosyl-(1-2)-β-D-glucopyranoside (1137099-42-3)

Guidance literature:

(11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1→3)-O-[3-O-(trans-cinnamoyl)-4-O-(2S-methylbutanoyl)-α-L-rhamnopyranosyl-(1→4)]-O-(2-O-n-decanoyl)-α-L-rhamnopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-O-β-D-glucopyranoside-(1,3''-lactone); With potassium hydroxide; at 90 ℃; for 2h;

With hydrogenchloride; In water; pH=4;

DOI:10.1016/j.phytochem.2013.07.006

Reference yield:

(11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1→3)-O-[2-O-(trans-cinnamoyl)-4-O-(2S-methylbutanoyl)-α-L-rhamnopyranosyl-(1→4)]-O-(2-O-n-decanoyl)-α-L-rhamnopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-O-β-D-glucopyranoside-(1,3''-lactone) (1467762-14-6) → (S)-2-Methylbutyric acid (1730-91-2) + 1-decanoic acid (334-48-5) + (E)-3-phenylacrylic acid (140-10-3) + (11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1-3)-O-[α-L-rhamnopyranosyl-(1-4)]-O-α-L-rhamnopyranosyl-(1-4)-O-α-L-rhamnopyranosyl-(1-2)-β-D-glucopyranoside (1137099-42-3)

Guidance literature:

(11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1→3)-O-[2-O-(trans-cinnamoyl)-4-O-(2S-methylbutanoyl)-α-L-rhamnopyranosyl-(1→4)]-O-(2-O-n-decanoyl)-α-L-rhamnopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-O-β-D-glucopyranoside-(1,3''-lactone); With potassium hydroxide; at 90 ℃; for 2h;

With hydrogenchloride; In water; pH=4;

DOI:10.1016/j.phytochem.2013.07.006

upstream raw materials:

batatoside M

batatoside N

(11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1→3)-O-[3-O-(trans-cinnamoyl)-4-O-(2S-methylbutanoyl)-α-L-rhamnopyranosyl-(1→4)]-O-(2-O-n-decanoyl)-α-L-rhamnopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-O-β-D-glucopyranoside-(1,3''-lactone)

(11S)-jalapinolic acid 11-O-α-L-rhamnopyranosyl-(1→3)-O-[2-O-(trans-cinnamoyl)-4-O-(2S-methylbutanoyl)-α-L-rhamnopyranosyl-(1→4)]-O-(2-O-n-decanoyl)-α-L-rhamnopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-O-β-D-glucopyranoside-(1,3''-lactone)