C₆₅H₆₄O₉S

Base Information

Chemical Name:C₆₅H₆₄O₉S
CAS No.:676609-66-8
Molecular Formula:C₆₅H₆₄O₉S
Molecular Weight:1021.28
Hs Code.:

C<sub>65</sub>H<sub>64</sub>O<sub>9</sub>S

Synonyms:C₆₅H₆₄O₉S

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Chemical Property of C₆₅H₆₄O₉S

Chemical Property:

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Technology Process of C₆₅H₆₄O₉S

There total 19 articles about C₆₅H₆₄O₉S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 676609-65-7
C₇₁H₇₈O₉SSi

: 676609-66-8
C₆₅H₆₄O₉S

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 0.5h;
DOI:10.1021/ol0364475

Reference yield:

: 939-26-4
2-bromomethylnaphthyl bromide

: 676609-66-8
C₆₅H₆₄O₉S

Guidance literature:: Multi-step reaction with 9 steps

1.1: 89 percent / NaH; TBAI / tetrahydrofuran / 3 h / 45 °C

2.1: aq. HCl / methanol; tetrahydrofuran / 25 h / 20 °C

3.1: 241 mg / 2,6-lutidine / CH₂Cl₂ / 0.17 h / 0 °C

4.1: 91 percent / CSA / tetrahydrofuran; methanol / 0.5 h / -5 °C

5.1: 41.5 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / 2 h / -60 - -45 °C

6.1: t-BuOK / tetrahydrofuran / 0.5 h / 0 °C

6.2: 36.2 mg / tetrahydrofuran / 0.83 h / 0 - 20 °C

7.1: 30.0 mg / TBAF / tetrahydrofuran / 1 h / 20 °C

8.1: AgOTf; 2,6-di-tert-butyl-4-methylpyridine / CH₂Cl₂ / 0.25 h / -50 °C

8.2: 60.2 mg / CH₂Cl₂ / 1 h / -50 - -30 °C

9.1: 54.1 mg / TBAF / tetrahydrofuran / 0.5 h / 20 °C

With 2,6-dimethylpyridine; hydrogenchloride; 2,6-di-tert-butyl-4-methylpyridine; oxalyl dichloride; camphor-10-sulfonic acid; potassium tert-butylate; tetrabutyl ammonium fluoride; silver trifluoromethanesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; methanol; dichloromethane; 5.1: Swern oxidation / 6.2: Wittig reaction;
DOI:10.1021/ol0364475

Reference yield:

: 676609-89-5
C₁₇H₂₄O₇

: 676609-66-8
C₆₅H₆₄O₉S

Guidance literature:: Multi-step reaction with 15 steps

1.1: 313 mg / PPTS / dimethylformamide / 12.5 h / 20 °C

2.1: 318 mg / NaH; TBAI / tetrahydrofuran / 0.58 h / 20 °C

3.1: 286 mg / DBU; (PPh₃)3RhCl / methanol; 1,2-dichloro-ethane / 0.25 h / 65 °C

4.1: 262 mg / pyridine / CH₂Cl₂ / 42 h / -18 - -5 °C

5.1: NaI; NiCl₂(PPh₃)2; n-BuLi / tetrahydrofuran; hexane / 0.5 h / 0 °C

5.2: 20 percent / t-BuCN / tetrahydrofuran; hexane / 2 h / 0 - 20 °C

6.1: 93 percent / TBAF / tetrahydrofuran / 20 °C

7.1: 89 percent / NaH; TBAI / tetrahydrofuran / 3 h / 45 °C

8.1: aq. HCl / methanol; tetrahydrofuran / 25 h / 20 °C

9.1: 241 mg / 2,6-lutidine / CH₂Cl₂ / 0.17 h / 0 °C

10.1: 91 percent / CSA / tetrahydrofuran; methanol / 0.5 h / -5 °C

11.1: 41.5 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / 2 h / -60 - -45 °C

12.1: t-BuOK / tetrahydrofuran / 0.5 h / 0 °C

12.2: 36.2 mg / tetrahydrofuran / 0.83 h / 0 - 20 °C

13.1: 30.0 mg / TBAF / tetrahydrofuran / 1 h / 20 °C

14.1: AgOTf; 2,6-di-tert-butyl-4-methylpyridine / CH₂Cl₂ / 0.25 h / -50 °C

14.2: 60.2 mg / CH₂Cl₂ / 1 h / -50 - -30 °C

15.1: 54.1 mg / TBAF / tetrahydrofuran / 0.5 h / 20 °C

With pyridine; 2,6-dimethylpyridine; hydrogenchloride; Wilkinson's catalyst; bis(triphenylphosphine)nickel(II) chloride; n-butyllithium; 2,6-di-tert-butyl-4-methylpyridine; oxalyl dichloride; camphor-10-sulfonic acid; potassium tert-butylate; tetrabutyl ammonium fluoride; silver trifluoromethanesulfonate; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; dimethyl sulfoxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; sodium iodide; In tetrahydrofuran; methanol; hexane; dichloromethane; 1,2-dichloro-ethane; N,N-dimethyl-formamide; 11.1: Swern oxidation / 12.2: Wittig reaction;
DOI:10.1021/ol0364475