2,12-Dibromo-7-phenyl-5,7,8,9-tetrahydro-6H-14-oxa-1,13-diaza-dibenzo[a,j]anthracene

Base Information

• Chemical Name: 2,12-Dibromo-7-phenyl-5,7,8,9-tetrahydro-6H-14-oxa-1,13-diaza-dibenzo[a,j]anthracene
• CAS No.: 130883-19-1
• Molecular Formula: C₂₅H₁₈Br₂N₂O
• Molecular Weight: 522.239
• Mol file: 130883-19-1.mol

Synonyms:2,12-Dibromo-7-phenyl-5,7,8,9-tetrahydro-6H-14-oxa-1,13-diaza-dibenzo[a,j]anthracene

Chemical Property of 2,12-Dibromo-7-phenyl-5,7,8,9-tetrahydro-6H-14-oxa-1,13-diaza-dibenzo[a,j]anthracene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,12-Dibromo-7-phenyl-5,7,8,9-tetrahydro-6H-14-oxa-1,13-diaza-dibenzo[a,j]anthracene

There total 1 articles about 2,12-Dibromo-7-phenyl-5,7,8,9-tetrahydro-6H-14-oxa-1,13-diaza-dibenzo[a,j]anthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-bromo-5,6,7,8-tetrahydro-8-quinolone (130861-70-0) → 2,12-Dibromo-7-phenyl-5,7,8,9-tetrahydro-6H-14-oxa-1,13-diaza-dibenzo[a,j]anthracene (130883-19-1)

Guidance literature:

With boron trifluoride diethyl etherate; at 110 ℃; for 0.5h;

DOI:10.1021/ja00001a027

Reference yield:

2,12-Dibromo-7-phenyl-5,7,8,9-tetrahydro-6H-14-oxa-1,13-diaza-dibenzo[a,j]anthracene (130883-19-1) → 2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylic acid (129337-84-4)

Guidance literature:

Multi-step reaction with 3 steps

2: 1.) magnesium, 1,2-dibromoethane, iodine, 2.) Ni(acac)2 / 1.) Et₂O, 50 deg C, 1 h, 2.) a) benzene, 0 deg C, 1 h, b) reflux, 24 h

3: 50 percent / boron trichloride / CH₂Cl₂; hexane / Heating

With bis(acetylacetonate)nickel(II); iodine; boron trichloride; magnesium; ethylene dibromide; In hexane; dichloromethane;

DOI:10.1021/ja00001a027

Reference yield:

2,12-Dibromo-7-phenyl-5,7,8,9-tetrahydro-6H-14-oxa-1,13-diaza-dibenzo[a,j]anthracene (130883-19-1) → methyl 2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate (129363-22-0)

Guidance literature:

Multi-step reaction with 2 steps

2: 1.) magnesium, 1,2-dibromoethane, iodine, 2.) Ni(acac)2 / 1.) Et₂O, 50 deg C, 1 h, 2.) a) benzene, 0 deg C, 1 h, b) reflux, 24 h

With bis(acetylacetonate)nickel(II); iodine; magnesium; ethylene dibromide;

DOI:10.1021/ja00001a027

upstream raw materials:

2-bromo-5,6,7,8-tetrahydro-8-quinolone

Downstream raw materials:

methyl 2,12-7-phenyl-5,6,7,8-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate

methyl 2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate

2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylic acid