Methanesulfonic acid (2R,3S)-3-pent-4-enyl-2-trimethylsilanyl-oxiranylmethyl ester

Base Information

Chemical Name:Methanesulfonic acid (2R,3S)-3-pent-4-enyl-2-trimethylsilanyl-oxiranylmethyl ester
CAS No.:188023-64-5
Molecular Formula:C₁₂H₂₄O₄SSi
Molecular Weight:292.472
Hs Code.:

Synonyms:Methanesulfonic acid (2R,3S)-3-pent-4-enyl-2-trimethylsilanyl-oxiranylmethyl ester

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Chemical Property of Methanesulfonic acid (2R,3S)-3-pent-4-enyl-2-trimethylsilanyl-oxiranylmethyl ester

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Technology Process of Methanesulfonic acid (2R,3S)-3-pent-4-enyl-2-trimethylsilanyl-oxiranylmethyl ester

There total 1 articles about Methanesulfonic acid (2R,3S)-3-pent-4-enyl-2-trimethylsilanyl-oxiranylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 65939-59-5
hept-1-en-6-yne

: 188023-64-5
Methanesulfonic acid (2R,3S)-3-pent-4-enyl-2-trimethylsilanyl-oxiranylmethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 30 min, 2.) THF, hexane, -78 deg C, 20 min

2: 1.) DIBAL, 2.) MeLi / 1.) toluene, Et₂O, 0 deg C to reflux, 1 h, 2.) toluene, Et₂O, 0 deg C

3: Ti(i-PrO)4, L-(+)-diethyl tartrate, t-BuOOH, MS 4 Angstroems / CH₂Cl₂ / 16 h / -20 °C

4: 86 percent / Et₃N / CH₂Cl₂ / 0.5 h / 0 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; n-butyllithium; diethyl (2R,3R)-tartrate; MS 4 Angstroems; methyllithium; diisobutylaluminium hydride; triethylamine; In dichloromethane;
DOI:10.1016/S0040-4020(98)00878-3

Reference yield:

: 188023-64-5
Methanesulfonic acid (2R,3S)-3-pent-4-enyl-2-trimethylsilanyl-oxiranylmethyl ester

: 100-51-6,185532-71-2
benzyl alcohol

: 188023-68-9
(3R)-3-benzyloxy-7-octen-2-one

Guidance literature:: With 18-crown-6 ether; potassium hydride; In tetrahydrofuran; at -78 ℃; Yield given;
DOI:10.1016/S0040-4039(96)02436-7

Reference yield:

: 188023-64-5
Methanesulfonic acid (2R,3S)-3-pent-4-enyl-2-trimethylsilanyl-oxiranylmethyl ester

: 146329-67-1
(R)-3-Hydroxy-2-octanone

Guidance literature:: Multi-step reaction with 2 steps

1: 18-crown-6 / tetrahydrofuran / 3 h / -78 °C

2: H₂ / Pd/C / methanol / 20 h

With 18-crown-6 ether; hydrogen; palladium on activated charcoal; In tetrahydrofuran; methanol;
DOI:10.1016/S0040-4020(98)00878-3