(E)-cyclohexyl 5-ethyl-3-(((trifluoromethyl)sulfonyl)oxy)hept-2-enoate

Base Information

Chemical Name:(E)-cyclohexyl 5-ethyl-3-(((trifluoromethyl)sulfonyl)oxy)hept-2-enoate
CAS No.:1427662-73-4
Molecular Formula:C₁₆H₂₅F₃O₅S
Molecular Weight:386.433
Hs Code.:

Synonyms:(E)-cyclohexyl 5-ethyl-3-(((trifluoromethyl)sulfonyl)oxy)hept-2-enoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-cyclohexyl 5-ethyl-3-(((trifluoromethyl)sulfonyl)oxy)hept-2-enoate

Chemical Property:

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Technology Process of (E)-cyclohexyl 5-ethyl-3-(((trifluoromethyl)sulfonyl)oxy)hept-2-enoate

There total 1 articles about (E)-cyclohexyl 5-ethyl-3-(((trifluoromethyl)sulfonyl)oxy)hept-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 358-23-6
trifluoromethylsulfonic anhydride

: 1427663-02-2
C₁₅H₂₆O₃

: 1427662-73-4
(E)-cyclohexyl 5-ethyl-3-(((trifluoromethyl)sulfonyl)oxy)hept-2-enoate

Guidance literature:: With tetramethyl ammoniumhydroxide; In hexane; water; at 5 - 15 ℃; Inert atmosphere;
DOI:10.1021/ja401606e

Reference yield: 76.0%

: 1427662-73-4
(E)-cyclohexyl 5-ethyl-3-(((trifluoromethyl)sulfonyl)oxy)hept-2-enoate

: (S)-(+)-cyclohexyl 5-ethylhepta-2,3-dienoate

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; C₅₉H₄₉O₃P; N-ethyl-N,N-diisopropylamine; In Isopropyl acetate; at 20 ℃; for 9h; Inert atmosphere;
DOI:10.1021/ja401606e

Reference yield:

: 1427662-73-4
(E)-cyclohexyl 5-ethyl-3-(((trifluoromethyl)sulfonyl)oxy)hept-2-enoate

: 1427662-74-5
(1R,2R,4S,E)-7-tert-butyl 2-cyclohexyl 3-(2-ethylbutylidene)-7-azabicyclo[2.2.1]hept-5-ene-2,7-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: N-ethyl-N,N-diisopropylamine; C₅₉H₄₉O₃P; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / Isopropyl acetate / 9 h / 20 °C / Inert atmosphere

2.1: aluminum (III) chloride / dichloromethane / 0.5 h / -78 °C / Inert atmosphere

2.2: 48 h / -78 °C / Inert atmosphere

With aluminum (III) chloride; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; C₅₉H₄₉O₃P; N-ethyl-N,N-diisopropylamine; In dichloromethane; Isopropyl acetate; 2.1: |Diels-Alder Cycloaddition;
DOI:10.1021/ja401606e