2-Bromo-1,10-phenanthroline

Base Information

Chemical Name:2-Bromo-1,10-phenanthroline
CAS No.:22426-14-8
Molecular Formula:C12H7 Br N2
Molecular Weight:259.105
Hs Code.:29339900
DSSTox Substance ID:DTXSID401310088
Mol file:22426-14-8.mol

Synonyms:2-BROMO-1,10-PHENANTHROLINE;22426-14-8;1,10-Phenanthroline, 2-bromo-;C12H7BrN2;MFCD13152102;bromophenanthroline;SCHEMBL809383;ZRJUDAZGVGIDLP-UHFFFAOYSA-N;DTXSID401310088;SMSSF-0625492;BCP26109;2-Bromo-1 pound not10-phenanthroline;AKOS015899602;AMS_CNC_ID-458950314;CS-W004619;DS-12821;SY038336;B4456;FT-0706846;J-508164

Suppliers and Price of 2-Bromo-1,10-phenanthroline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
tert-Butyl1-(Furan-2-ylmethyl)pyrrolidine-2-carboxylate
10mg
$ 45.00

TCI Chemical
2-Bromo-1,10-phenanthroline >98.0%(T)
1g
$ 55.00

TCI Chemical
2-Bromo-1,10-phenanthroline >98.0%(T)
5g
$ 164.00

Sigma-Aldrich
2-Bromo-1,10-phenanthroline
1g
$ 241.00

Matrix Scientific
2-Bromo-1,10-phenanthroline 95+%
10g
$ 1008.00

Matrix Scientific
2-Bromo-1,10-phenanthroline 95+%
5g
$ 672.00

Matrix Scientific
2-Bromo-1,10-phenanthroline 95+%
1g
$ 246.00

Crysdot
2-Bromo-1,10-phenanthroline 97%
10g
$ 238.00

ChemScene
2-Bromo-1,10-phenanthroline 97.49%
1g
$ 23.00

ChemScene
2-Bromo-1,10-phenanthroline 97.49%
5g
$ 88.00

Total 87 raw suppliers

Chemical Property of 2-Bromo-1,10-phenanthroline

Chemical Property:

Melting Point:161.0 to 165.0 °C
Boiling Point:414.3±25.0 °C(Predicted)
PKA:4.20±0.10(Predicted)
PSA：25.78000
Density:1.616
LogP:3.54550
Storage Temp.:Keep in dark place,Sealed in dry,Room Temperature
XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:257.97926
Heavy Atom Count:15
Complexity:234

Purity/Quality:

97% ^*data from raw suppliers

tert-Butyl1-(Furan-2-ylmethyl)pyrrolidine-2-carboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 41
Safety Statements: 26-39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC2=C(C3=C(C=C2)C=CC(=N3)Br)N=C1
Uses Brominated phenanthroline can be synthesized via a method reported by Baran and coworkers using a two-step protocol through N-Oxide formation using m-CBPA (Aldrich 273031) and bromination using TBAB (Sigma-Aldrich 426288) and p-Toluenesulfonic anhydride (Aldrich 259764).

Technology Process of 2-Bromo-1,10-phenanthroline

There total 6 articles about 2-Bromo-1,10-phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 31535-89-4
1-methyl-1,10-phenanthrolin-2(1H)-one

: 22426-14-8
2--bromo-1,10--phenanthroline

Guidance literature:: 1-methyl-1,10-phenanthrolin-2(1H)-one; With phosphorus pentabromide; phosphorus(V) oxybromide; at 20 - 80 ℃; Inert atmosphere;

With ammonia; In water; Alkaline conditions;

Reference yield: 75.0%

: 66-71-7
1,10-Phenanthroline

CBr₄: CBr₄

: 31535-89-4
1-methyl-1,10-phenanthrolin-2(1H)-one

: 24721-92-4
1-Dimethylamino-ethanol

: 22426-14-8
2--bromo-1,10--phenanthroline

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane;

Reference yield: 70.0%

: 1891-19-6
1,10-phenanthroline N-oxide

: 22426-14-8
2--bromo-1,10--phenanthroline

Guidance literature:: 1,10-phenanthroline N-oxide; With tetrabutylammomium bromide; In dichloromethane; at 20 ℃; for 0.166667h; Inert atmosphere; Molecular sieve;

With p-toluenesulfonylanhydride; In dichloromethane; at 20 ℃; regioselective reaction; Inert atmosphere;
DOI:10.1021/ol3034675