(C₅H₅)2ZrCOCH₂CH(CH₂)5Cl

Base Information

• Chemical Name: (C₅H₅)2ZrCOCH₂CH(CH₂)5Cl
• CAS No.: 71068-71-8
• Molecular Formula: C₁₈H₂₃ClOZr
• Molecular Weight: 382.057
• Mol file: 71068-71-8.mol

Synonyms:(C₅H₅)2ZrCOCH₂CH(CH₂)5Cl

Chemical Property of (C₅H₅)2ZrCOCH₂CH(CH₂)5Cl

Chemical Property:

Purity/Quality:

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Technology Process of (C₅H₅)2ZrCOCH₂CH(CH₂)5Cl

There total 1 articles about (C₅H₅)2ZrCOCH₂CH(CH₂)5Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(C5H5)2ZrClCH2CH(CH2)5 (54634-15-0) → (C5H5)2ZrCOCH2CH(CH2)5Cl (71068-71-8)

Guidance literature:

With CO; In dichloromethane; carbonylation for 30 min (Ar); full react. time 3 h; concn., addn. of hexane. cooling; recrystn. from CH2Cl2/hexane; elem. anal.;

DOI:10.1021/ja00371a012

Reference yield: 50.0%

Schwartz's reagent + (C5H5)2ZrCOCH2CH(CH2)5Cl (71068-71-8) → zirconocene dichloride (1291-32-3) + (C5H5)2(Cl)Zr(OCHCH2(C6H11))Zr(Cl)(C5H5)2

Guidance literature:

In toluene; stirring for 12 h (Ar); NMR monitoring; treating with CH2Cl2, recrystn. from toluene/octane; elem. anal.;

DOI:10.1021/ja00371a012

upstream raw materials:

(C₅H₅)2ZrClCH₂CH(CH₂)5

Downstream raw materials:

zirconocene dichloride