Technology Process of (1R,2R,3R,4S,SS)-2-<3-(p-tolylsulfinyl)-2-furoyl>-3-methylbicyclo<2.2.1>heptane
There total 4 articles about (1R,2R,3R,4S,SS)-2-<3-(p-tolylsulfinyl)-2-furoyl>-3-methylbicyclo<2.2.1>heptane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
hydrogen;
palladium on activated charcoal;
In
methanol;
for 2h;
under 760 Torr;
DOI:10.1248/cpb.46.1078
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) LDA / 1.) THF, hexane, -78 deg C, 2.) THF, hexane
2: 73 percent / MnO2 / CHCl3 / 0.5 h / Ambient temperature
3: AlCl3 / CH2Cl2 / 3 h / 25 °C
4: 60 percent / H2 / 5 percent Pd/C / methanol / 2 h / 760 Torr
With
manganese(IV) oxide; aluminium trichloride; hydrogen; lithium diisopropyl amide;
palladium on activated charcoal;
In
methanol; dichloromethane; chloroform;
DOI:10.1248/cpb.46.1078
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 73 percent / MnO2 / CHCl3 / 0.5 h / Ambient temperature
2: AlCl3 / CH2Cl2 / 3 h / 25 °C
3: 60 percent / H2 / 5 percent Pd/C / methanol / 2 h / 760 Torr
With
manganese(IV) oxide; aluminium trichloride; hydrogen;
palladium on activated charcoal;
In
methanol; dichloromethane; chloroform;
DOI:10.1248/cpb.46.1078
