3,8-Diamino-5-(5-aminopentyl)-6-phenylphenanthridinium bromide hydrobromide salt

Base Information

• Chemical Name: 3,8-Diamino-5-(5-aminopentyl)-6-phenylphenanthridinium bromide hydrobromide salt
• CAS No.: 264619-14-9
• Molecular Formula: BrH*Br*C₂₄H₂₇N₄
• Molecular Weight: 532.321
• Mol file: 264619-14-9.mol

Synonyms:3,8-Diamino-5-(5-aminopentyl)-6-phenylphenanthridinium bromide hydrobromide salt

Chemical Property of 3,8-Diamino-5-(5-aminopentyl)-6-phenylphenanthridinium bromide hydrobromide salt

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 3,8-Diamino-5-(5-aminopentyl)-6-phenylphenanthridinium bromide hydrobromide salt

There total 3 articles about 3,8-Diamino-5-(5-aminopentyl)-6-phenylphenanthridinium bromide hydrobromide salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

3,8-Bis(ethoxycarbonylamino)-6-phenyl-5-(5-trifluoroacetamidopentyl)phenanthridinium trifluoromethanesulfonate → 3,8-Diamino-5-(5-aminopentyl)-6-phenylphenanthridinium bromide hydrobromide salt (264619-14-9)

Guidance literature:

With water; hydrogen bromide; for 18h; Heating;

DOI:10.1039/a908389h

Reference yield:

2,2,2-trifluoro-N-(5-hydroxypentyl)acetamide (128238-44-8) → 3,8-Diamino-5-(5-aminopentyl)-6-phenylphenanthridinium bromide hydrobromide salt (264619-14-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 81 percent / poly(vinylpyridine) / CH₂Cl₂ / 0.08 h / 20 °C

2: 49 percent / nitrobenzene / 18 h / 20 °C

3: 83 percent / HBr; H₂O / 18 h / Heating

With poly(vinylpyridine); water; hydrogen bromide; In dichloromethane; nitrobenzene; 1: Substitution / 2: Alkylation / 3: Hydrolysis;

DOI:10.1039/a908389h

Reference yield:

5-(Trifluoroacetamido)pentyl triflate (170219-97-3) → 3,8-Diamino-5-(5-aminopentyl)-6-phenylphenanthridinium bromide hydrobromide salt (264619-14-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 49 percent / nitrobenzene / 18 h / 20 °C

2: 83 percent / HBr; H₂O / 18 h / Heating

With water; hydrogen bromide; In nitrobenzene; 1: Alkylation / 2: Hydrolysis;

DOI:10.1039/a908389h

upstream raw materials:

2,2,2-trifluoro-N-(5-hydroxypentyl)acetamide

5-(Trifluoroacetamido)pentyl triflate