Acetic acid (1R,5R,6S)-3-((3R,4S,6R)-6-acetoxy-4-benzyloxymethoxy-3-chloro-cyclohept-1-enylmethyl)-6-benzyloxymethoxy-5-chloro-cyclohept-3-enyl ester

Base Information

Chemical Name:Acetic acid (1R,5R,6S)-3-((3R,4S,6R)-6-acetoxy-4-benzyloxymethoxy-3-chloro-cyclohept-1-enylmethyl)-6-benzyloxymethoxy-5-chloro-cyclohept-3-enyl ester
CAS No.:609769-08-6
Molecular Formula:C₃₅H₄₂Cl₂O₈
Molecular Weight:661.62
Hs Code.:

Acetic acid (1R,5R,6S)-3-((3R,4S,6R)-6-acetoxy-4-benzyloxymethoxy-3-chloro-cyclohept-1-enylmethyl)-6-benzyloxymethoxy-5-chloro-cyclohept-3-enyl ester

Synonyms:Acetic acid (1R,5R,6S)-3-((3R,4S,6R)-6-acetoxy-4-benzyloxymethoxy-3-chloro-cyclohept-1-enylmethyl)-6-benzyloxymethoxy-5-chloro-cyclohept-3-enyl ester

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Chemical Property of Acetic acid (1R,5R,6S)-3-((3R,4S,6R)-6-acetoxy-4-benzyloxymethoxy-3-chloro-cyclohept-1-enylmethyl)-6-benzyloxymethoxy-5-chloro-cyclohept-3-enyl ester

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Technology Process of Acetic acid (1R,5R,6S)-3-((3R,4S,6R)-6-acetoxy-4-benzyloxymethoxy-3-chloro-cyclohept-1-enylmethyl)-6-benzyloxymethoxy-5-chloro-cyclohept-3-enyl ester

There total 1 articles about Acetic acid (1R,5R,6S)-3-((3R,4S,6R)-6-acetoxy-4-benzyloxymethoxy-3-chloro-cyclohept-1-enylmethyl)-6-benzyloxymethoxy-5-chloro-cyclohept-3-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 3587-60-8
Benzyloxymethyl chloride

: 339266-73-8
(+)-1,1'-methylenedi[(1S,1'S,3S,3'S,5S,5'S)-8-oxabicyclo[3.2.1]oct-6-en-3-yl] diacetate

: 609769-08-6
Acetic acid (1R,5R,6S)-3-((3R,4S,6R)-6-acetoxy-4-benzyloxymethoxy-3-chloro-cyclohept-1-enylmethyl)-6-benzyloxymethoxy-5-chloro-cyclohept-3-enyl ester

Guidance literature:: (+)-1,1'-methylenedi[(1S,1'S,3S,3'S,5S,5'S)-8-oxabicyclo[3.2.1]oct-6-en-3-yl] diacetate; With boron trichloride; In dichloromethane; at 0 ℃; for 0.5h;

Benzyloxymethyl chloride; With N-ethyl-N,N-diisopropylamine; tetra-(n-butyl)ammonium iodide; In dichloromethane; at 25 ℃; for 13h; Further stages.;
DOI:10.1002/ejoc.200300224

Reference yield: 70.0%

: 609769-08-6
Acetic acid (1R,5R,6S)-3-((3R,4S,6R)-6-acetoxy-4-benzyloxymethoxy-3-chloro-cyclohept-1-enylmethyl)-6-benzyloxymethoxy-5-chloro-cyclohept-3-enyl ester

: 609769-09-7
(1R,1'R,6R,6'R)-3,3'-methylenebis{6-[(benzyloxy)methoxy]-cyclohept-3-en-1-yl} diacetate

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In toluene; at 80 ℃; for 2h;
DOI:10.1002/ejoc.200300224

Reference yield:

: 609769-08-6
Acetic acid (1R,5R,6S)-3-((3R,4S,6R)-6-acetoxy-4-benzyloxymethoxy-3-chloro-cyclohept-1-enylmethyl)-6-benzyloxymethoxy-5-chloro-cyclohept-3-enyl ester

: 609769-10-0
(1R,1'R,6R,6'R)-3,3'-methylenebis{6-[(benzyloxy)methoxy]-cyclohept-3-en-1-ol}

Guidance literature:: Multi-step reaction with 2 steps

1: 70 percent / AIBN; Bu₃SnH / toluene / 2 h / 80 °C

2: 97 percent / K₂CO₃ / methanol / 4 h / 25 °C

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; potassium carbonate; In methanol; toluene;
DOI:10.1002/ejoc.200300224