(-)-(1R,6R,8R)-8-<(benzyloxy)methyl>-3-phenyl-2,4-dioxabicyclo<4.3.0>nonane

Base Information

Chemical Name:(-)-(1R,6R,8R)-8-<(benzyloxy)methyl>-3-phenyl-2,4-dioxabicyclo<4.3.0>nonane
CAS No.:120905-28-4
Molecular Formula:C₂₁H₂₄O₃
Molecular Weight:324.42
Hs Code.:

Synonyms:(-)-(1R,6R,8R)-8-<(benzyloxy)methyl>-3-phenyl-2,4-dioxabicyclo<4.3.0>nonane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (-)-(1R,6R,8R)-8-<(benzyloxy)methyl>-3-phenyl-2,4-dioxabicyclo<4.3.0>nonane

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Technology Process of (-)-(1R,6R,8R)-8-<(benzyloxy)methyl>-3-phenyl-2,4-dioxabicyclo<4.3.0>nonane

There total 1 articles about (-)-(1R,6R,8R)-8-<(benzyloxy)methyl>-3-phenyl-2,4-dioxabicyclo<4.3.0>nonane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1125-88-8
benzaldehyde dimethyl acetal

: 120905-28-4
(-)-(1R,6R,8R)-8-<(benzyloxy)methyl>-3-phenyl-2,4-dioxabicyclo<4.3.0>nonane

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / HBF₄ / dimethylformamide; diethyl ether / 3.5 h / Ambient temperature

2: 1.) KH / 1.) THF, room temperature, 20 min, 2.) 12 h

With tetrafluoroboric acid; potassium hydride; In diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jm00128a029

Reference yield: 98.0%

: 120905-28-4
(-)-(1R,6R,8R)-8-<(benzyloxy)methyl>-3-phenyl-2,4-dioxabicyclo<4.3.0>nonane

: 120236-98-8
(-)-(1R,2R,4R)-4-<(benzyloxy)methyl>-2-hydroxycyclopentanemethanol

Guidance literature:: With sulfuric acid; In water; for 0.166667h; Heating;
DOI:10.1021/jm00128a029

Reference yield:

: 120905-28-4
(-)-(1R,6R,8R)-8-<(benzyloxy)methyl>-3-phenyl-2,4-dioxabicyclo<4.3.0>nonane

: 120905-32-0
(+)-(1R,3S,4R)-3-acetoxy-4-<(benzoyloxy)methyl>cyclopentanemethanol

Guidance literature:: Multi-step reaction with 5 steps

1: 98 percent / conc. H₂SO₄ / H₂O / 0.17 h / Heating

2: 99 percent / pyridine / CH₂Cl₂ / 0.17 h

3: 90 percent / Et₃N / CH₂Cl₂ / 3 h / Ambient temperature

4: 58 percent / dimethylsulfoxide / 40 - 45 °C

5: 100 percent / H₂ / 5percent Pd/C / ethanol / 3000.2 Torr

With pyridine; sulfuric acid; hydrogen; triethylamine; palladium on activated charcoal; In ethanol; dichloromethane; water; dimethyl sulfoxide;
DOI:10.1021/jm00128a029