Chemical Property of MANGANESE(II) CHLORIDE HYDRATE
Chemical Property:
- Melting Point:122 °C(lit.)
- Boiling Point:85 oC (15 mmHg)
- Flash Point:83 oC
- PSA：9.23000
- Density:1.913 g/mL at 25oC(lit.)
- LogP:1.31470
- Storage Temp.:Hygroscopic, Room Temperature, under inert atmosphere
- Solubility.:Methanol (Slightly), Water (Slightly)
- Hydrogen Bond Donor Count:1
- Hydrogen Bond Acceptor Count:1
- Rotatable Bond Count:0
- Exact Mass:142.886313
- Heavy Atom Count:4
- Complexity:2.8
- Purity/Quality:
-
98%,99%, *data from raw suppliers
Manganese(II) chloride monohydrate *data from reagent suppliers
Safty Information:
- Pictogram(s):
Xn
- Hazard Codes:Xn
- Statements:
22-36/37/38-52
- Safety Statements:
26-36/37-45-61-36-22
- MSDS Files:
-
SDS file from LookChem
Useful:
- Canonical SMILES:O.Cl[Mn]Cl
-
Uses
Starting material for preparation of organomanganese chloride reagents; in combination with RLi or RMgX catalyzes reduction of vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- andstereo-selectively.
