4,5-[Di(tert-butyl)silylenedioxy]-7,8-dimethoxy-2,2-tetramethylene-9-phenylsulfinyl-2,3-dihydrobenz[f]indene-1,3-dione

Base Information

Chemical Name:4,5-[Di(tert-butyl)silylenedioxy]-7,8-dimethoxy-2,2-tetramethylene-9-phenylsulfinyl-2,3-dihydrobenz[f]indene-1,3-dione
CAS No.:317350-30-4
Molecular Formula:C₃₃H₃₈O₇SSi
Molecular Weight:606.812
Hs Code.:

Synonyms:4,5-[Di(tert-butyl)silylenedioxy]-7,8-dimethoxy-2,2-tetramethylene-9-phenylsulfinyl-2,3-dihydrobenz[f]indene-1,3-dione

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Chemical Property of 4,5-[Di(tert-butyl)silylenedioxy]-7,8-dimethoxy-2,2-tetramethylene-9-phenylsulfinyl-2,3-dihydrobenz[f]indene-1,3-dione

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Technology Process of 4,5-[Di(tert-butyl)silylenedioxy]-7,8-dimethoxy-2,2-tetramethylene-9-phenylsulfinyl-2,3-dihydrobenz[f]indene-1,3-dione

There total 7 articles about 4,5-[Di(tert-butyl)silylenedioxy]-7,8-dimethoxy-2,2-tetramethylene-9-phenylsulfinyl-2,3-dihydrobenz[f]indene-1,3-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 317350-60-0
4,5-[Di(tert-butyl)silylenedioxy]-7,8-dimethoxy-2,2-tetramethylene-9-phenylthio-2,3-dihydrobenz[f]indene-1,3-dione

: 317350-30-4
4,5-[Di(tert-butyl)silylenedioxy]-7,8-dimethoxy-2,2-tetramethylene-9-phenylsulfinyl-2,3-dihydrobenz[f]indene-1,3-dione

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -40 ℃; for 0.5h;
DOI:10.1002/1521-3765(20001103)6:21<3897::AID-CHEM3897>3.0.CO;2-1

Reference yield:

: 137709-52-5
1-(2-Methyl-[1,3]dioxolan-2-yl)-cyclopentanecarbaldehyde

: 317350-30-4
4,5-[Di(tert-butyl)silylenedioxy]-7,8-dimethoxy-2,2-tetramethylene-9-phenylsulfinyl-2,3-dihydrobenz[f]indene-1,3-dione

Guidance literature:: Multi-step reaction with 7 steps

1.1: nBuLi; HMPA / hexane; tetrahydrofuran / 0.5 h / -50 °C

1.2: 81 percent / hexane; tetrahydrofuran / 0.67 h / -50 °C

2.1: 98 percent / p-TsOH*H₂O / acetone / 1 h / 20 °C

3.1: 100 percent / 4-(dimethylamino)pyridine / CH₂Cl₂ / 2 h / 20 °C

4.1: 88 percent / LiN(TMS)2 / tetrahydrofuran / 0.5 h / -78 °C

5.1: 64 percent / DMSO; PCC; pyridinium trifluoroacetate / benzene / 1 h / 20 °C

6.1: 57 percent

7.1: 78 percent / mCPBA / CH₂Cl₂ / 0.5 h / -40 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; n-butyllithium; pyridinium trifluroacetate; toluene-4-sulfonic acid; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; lithium hexamethyldisilazane; In tetrahydrofuran; hexane; dichloromethane; acetone; benzene;
DOI:10.1002/1521-3765(20001103)6:21<3897::AID-CHEM3897>3.0.CO;2-1

Reference yield:

: 317350-58-6
3-Hydroxy-4,4-tetramethylene-1-phenylthio-1-hexyn-5-one

: 317350-30-4
4,5-[Di(tert-butyl)silylenedioxy]-7,8-dimethoxy-2,2-tetramethylene-9-phenylsulfinyl-2,3-dihydrobenz[f]indene-1,3-dione

Guidance literature:: Multi-step reaction with 5 steps

1: 100 percent / 4-(dimethylamino)pyridine / CH₂Cl₂ / 2 h / 20 °C

2: 88 percent / LiN(TMS)2 / tetrahydrofuran / 0.5 h / -78 °C

3: 64 percent / DMSO; PCC; pyridinium trifluoroacetate / benzene / 1 h / 20 °C

4: 57 percent

5: 78 percent / mCPBA / CH₂Cl₂ / 0.5 h / -40 °C

With dmap; pyridinium trifluroacetate; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; lithium hexamethyldisilazane; In tetrahydrofuran; dichloromethane; benzene;
DOI:10.1002/1521-3765(20001103)6:21<3897::AID-CHEM3897>3.0.CO;2-1