benzoic acid 3-(diethyl-isopropyl-silanyloxy)-4-(11-ethyl-3,17-dimethoxy-7,9,13,15-tetramethyl-18-oxo-10,12-bis-triethylsilanyloxy-oxacyclooctadeca-4,6,14,16-tetraen-2-yl)-1,2-dimethyl-pentyl ester

Base Information

Chemical Name:benzoic acid 3-(diethyl-isopropyl-silanyloxy)-4-(11-ethyl-3,17-dimethoxy-7,9,13,15-tetramethyl-18-oxo-10,12-bis-triethylsilanyloxy-oxacyclooctadeca-4,6,14,16-tetraen-2-yl)-1,2-dimethyl-pentyl ester
CAS No.:273944-75-5
Molecular Formula:C₅₈H₁₀₂O₉Si₃
Molecular Weight:1027.7
Hs Code.:

benzoic acid 3-(diethyl-isopropyl-silanyloxy)-4-(11-ethyl-3,17-dimethoxy-7,9,13,15-tetramethyl-18-oxo-10,12-bis-triethylsilanyloxy-oxacyclooctadeca-4,6,14,16-tetraen-2-yl)-1,2-dimethyl-pentyl ester

Synonyms:benzoic acid 3-(diethyl-isopropyl-silanyloxy)-4-(11-ethyl-3,17-dimethoxy-7,9,13,15-tetramethyl-18-oxo-10,12-bis-triethylsilanyloxy-oxacyclooctadeca-4,6,14,16-tetraen-2-yl)-1,2-dimethyl-pentyl ester

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Chemical Property of benzoic acid 3-(diethyl-isopropyl-silanyloxy)-4-(11-ethyl-3,17-dimethoxy-7,9,13,15-tetramethyl-18-oxo-10,12-bis-triethylsilanyloxy-oxacyclooctadeca-4,6,14,16-tetraen-2-yl)-1,2-dimethyl-pentyl ester

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Technology Process of benzoic acid 3-(diethyl-isopropyl-silanyloxy)-4-(11-ethyl-3,17-dimethoxy-7,9,13,15-tetramethyl-18-oxo-10,12-bis-triethylsilanyloxy-oxacyclooctadeca-4,6,14,16-tetraen-2-yl)-1,2-dimethyl-pentyl ester

There total 24 articles about benzoic acid 3-(diethyl-isopropyl-silanyloxy)-4-(11-ethyl-3,17-dimethoxy-7,9,13,15-tetramethyl-18-oxo-10,12-bis-triethylsilanyloxy-oxacyclooctadeca-4,6,14,16-tetraen-2-yl)-1,2-dimethyl-pentyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: C₅₈H₁₀₄O₁₀Si₃

: 273944-75-5
benzoic acid 3-(diethyl-isopropyl-silanyloxy)-4-(11-ethyl-3,17-dimethoxy-7,9,13,15-tetramethyl-18-oxo-10,12-bis-triethylsilanyloxy-oxacyclooctadeca-4,6,14,16-tetraen-2-yl)-1,2-dimethyl-pentyl ester

Guidance literature:: With dmap; 2,4,6-trichlorobenzoyl chloride; triethylamine; In toluene; at 20 ℃; for 18h; Inert atmosphere;
DOI:10.1016/j.tet.2011.09.012

Reference yield: 69.0%

: 273944-74-4
Benzoic acid (7E,9E,17E,19Z)-(1R,2R,3R,4R,5R,6S,12R,13S,14S,15R,16R)-20-carboxy-3-(diethyl-isopropyl-silanyloxy)-14-ethyl-5-hydroxy-6,20-dimethoxy-1,2,4,10,12,16,18-heptamethyl-13,15-bis-triethylsilanyloxy-icosa-7,9,17,19-tetraenyl ester

: 273944-75-5
benzoic acid 3-(diethyl-isopropyl-silanyloxy)-4-(11-ethyl-3,17-dimethoxy-7,9,13,15-tetramethyl-18-oxo-10,12-bis-triethylsilanyloxy-oxacyclooctadeca-4,6,14,16-tetraen-2-yl)-1,2-dimethyl-pentyl ester

Guidance literature:: With dmap; 2,4,6-trichlorobenzoyl chloride; triethylamine; In toluene; at 20 ℃; for 18h;
DOI:10.1002/(SICI)1521-3773(20000403)39:7<1308::AID-ANIE1308>3.0.CO;2-7

Reference yield:

: 273944-63-1
(1E,3S,4R,5R,6R,7R,8R)-1-tributylstannyl-8-benzoyloxy-6-diethylisopropylsilyloxy-4-hydroxy-3-methoxy-5,7-dimethylnon-1-ene

: 273944-77-7
(2Z,4E,6R,7R,8S,9S,10R,12E)-7,9-ditriethylsilyloxy-8-ethyl-13-iodo-2-methoxy-4,6,10,12-tetramethyltrideca-2,4,12-trienoic acid

: 273944-75-5
benzoic acid 3-(diethyl-isopropyl-silanyloxy)-4-(11-ethyl-3,17-dimethoxy-7,9,13,15-tetramethyl-18-oxo-10,12-bis-triethylsilanyloxy-oxacyclooctadeca-4,6,14,16-tetraen-2-yl)-1,2-dimethyl-pentyl ester

Guidance literature:: (1E,3S,4R,5R,6R,7R,8R)-1-tributylstannyl-8-benzoyloxy-6-diethylisopropylsilyloxy-4-hydroxy-3-methoxy-5,7-dimethylnon-1-ene; (2Z,4E,6R,7R,8S,9S,10R,12E)-7,9-ditriethylsilyloxy-8-ethyl-13-iodo-2-methoxy-4,6,10,12-tetramethyltrideca-2,4,12-trienoic acid; With dmap; 2,4,6-trichlorobenzoyl chloride; triethylamine; In toluene; at 20 ℃; for 16h; Inert atmosphere;

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; N,N-dimethyl-formamide; at 60 ℃; for 16h; Inert atmosphere;
DOI:10.1016/j.tet.2011.09.012