C₃₂H₅₆O₁₄Si₂

Base Information

• Chemical Name: C₃₂H₅₆O₁₄Si₂
• CAS No.: 861114-04-7
• Molecular Formula: C₃₂H₅₆O₁₄Si₂
• Molecular Weight: 720.959
• Mol file: 861114-04-7.mol

Synonyms:C₃₂H₅₆O₁₄Si₂

Chemical Property of C₃₂H₅₆O₁₄Si₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₂H₅₆O₁₄Si₂

There total 1 articles about C₃₂H₅₆O₁₄Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C39H62O14Si2 (861114-00-3) → C32H56O14Si2 (861114-04-7) + C39H68O14Si2

Guidance literature:

With hydrogen; palladium dihydroxide; In ethanol;

DOI:10.1002/anie.200500217

Reference yield:

C32H56O14Si2 (861114-04-7) → C30H32O11

Guidance literature:

Multi-step reaction with 14 steps

1.1: base

2.1: NaBH₄ / methanol / 0.5 h / 0 - 25 °C

3.1: Pb(OAc)4 / CH₂Cl₂ / 2 h / 0 - 25 °C

4.1: 70 percent / DBU / toluene / 4 h / Heating

5.1: SOCl₂; pyridine / 8 h / 0 - 25 °C

5.2: K₂CO₃; MeOH / 2 h / 25 °C

6.1: Br₂; N,N-dimethylaniline; K₂CO₃ / CH₂Cl₂ / 0.17 h / -78 °C

6.2: 76 percent / N,N-dimethylaniline; K₂CO₃ / CH₂Cl₂ / 3 h / -78 - 0 °C

7.1: 42 percent / (Me₃Si)3SiH; AIBN / toluene / 0.5 h / 110 °C

8.1: 88 percent / NaBH₄ / methanol / 0.25 h / 0 °C

9.1: pyridine; DMAP / 5 h / 60 °C

10.1: HCl / methanol; diethyl ether / 4 h / 0 - 25 °C

11.1: 79 percent / Et₃N; DMAP / CH₂Cl₂ / 6 h / 0 - 25 °C

12.1: H₂SO₄ / CH₂Cl₂ / 0.5 h / 0 °C

13.1: PCC / 1,2-dichloro-ethane / 16 h / 65 °C

14.1: K₂CO₃; MeOH / 0.5 h / 25 °C

With pyridine; lead(IV) acetate; hydrogenchloride; methanol; dmap; sodium tetrahydroborate; thionyl chloride; 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane; sulfuric acid; bromine; potassium carbonate; N,N-dimethyl-aniline; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; pyridinium chlorochromate; In methanol; diethyl ether; dichloromethane; 1,2-dichloro-ethane; toluene;

DOI:10.1002/anie.200500217

Reference yield:

C32H56O14Si2 (861114-04-7) → C31H36O11 (861114-12-7)

Guidance literature:

Multi-step reaction with 10 steps

1.1: base

2.1: NaBH₄ / methanol / 0.5 h / 0 - 25 °C

3.1: Pb(OAc)4 / CH₂Cl₂ / 2 h / 0 - 25 °C

4.1: 70 percent / DBU / toluene / 4 h / Heating

5.1: SOCl₂; pyridine / 8 h / 0 - 25 °C

5.2: K₂CO₃; MeOH / 2 h / 25 °C

6.1: Br₂; N,N-dimethylaniline; K₂CO₃ / CH₂Cl₂ / 0.17 h / -78 °C

6.2: 76 percent / N,N-dimethylaniline; K₂CO₃ / CH₂Cl₂ / 3 h / -78 - 0 °C

7.1: 42 percent / (Me₃Si)3SiH; AIBN / toluene / 0.5 h / 110 °C

8.1: 88 percent / NaBH₄ / methanol / 0.25 h / 0 °C

9.1: pyridine; DMAP / 5 h / 60 °C

10.1: HCl / methanol; diethyl ether / 4 h / 0 - 25 °C

With pyridine; lead(IV) acetate; hydrogenchloride; dmap; sodium tetrahydroborate; thionyl chloride; 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane; bromine; potassium carbonate; N,N-dimethyl-aniline; 1,8-diazabicyclo[5.4.0]undec-7-ene; In methanol; diethyl ether; dichloromethane; toluene;

DOI:10.1002/anie.200500217

upstream raw materials:

C₃₉H₆₂O₁₄Si₂

Downstream raw materials:

C₃₁H₃₆O₁₁

C₃₅H₄₀O₁₃

C₃₄H₃₆O₁₃

C₃₄H₃₈O₁₃