bis(4-chlorophenyl) carbonate

Base Information

• Chemical Name: bis(4-chlorophenyl) carbonate
• CAS No.: 2167-53-5
• Molecular Formula: C13H8 Cl2 O3
• Molecular Weight: 283.111
• Mol file: 2167-53-5.mol

Synonyms:Carbonicacid, bis(p-chlorophenyl)ester (6CI,7CI,8CI); Bis(4-chlorophenyl) carbonate; Bis(p-chlorophenyl) carbonate;NSC 405027

Chemical Property of bis(4-chlorophenyl) carbonate

Chemical Property:

• Vapor Pressure: 1.3E-05mmHg at 25°C
• Boiling Point: 368.1°Cat760mmHg
• Flash Point: 149.3°C
• Density: 1.395g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(4-chlorophenyl) carbonate

There total 19 articles about bis(4-chlorophenyl) carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.5%

→ bis(4-chlorophenyl) carbonate (2167-53-5)

Guidance literature:

Reference yield: 94.0%

4-chlorophenyl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylate + 4-chloro-phenol (106-48-9,82344-39-6) → bis(4-chlorophenyl) carbonate (2167-53-5)

Guidance literature:

With aluminum (III) chloride; In toluene; at 20 ℃; for 0.666667h;

DOI:10.5012/bkcs.2014.35.9.2758

Reference yield: 90.0%

tris(p-chlorophenyl)methanol (3010-80-8) → bis(4-chlorophenyl) carbonate (2167-53-5)

Guidance literature:

With trifluoroacetyl peroxide; trifluoroacetic acid; In 1,1,2-Trichloro-1,2,2-trifluoroethane; at -25 ℃; for 1h;

DOI:10.1021/ol049171p

upstream raw materials:

bis(phenyl) carbonate

sodium 4-chlorophenolate

trichloromethyl chloroformate

4-chlorophenyl cyanate

Downstream raw materials:

ethyl p-chlorophenylmethylcarbamate

2-acetoxy-2-(p-chlorophenoxy)-5,5-dimethyl-Δ³-1,3,4-oxadiazoline

acetone p-chlorophenoxycarbonyl hydrazone

p-chlorophenyl hydrazinecarboxylate

Refernces

• 1、 Moon, Hyun Kyung,Sung, Gi Hyeon,Yoon, Yong-Jin,Yoon, Hyo Jae. "Alkyl and aryl 4,5-dichloro-6-oxopyridazin-1(6 H)-carboxylates: A practical alternative to chloroformates for the synthesis of symmetric and asymmetric carbonates". supporting information. p. 1577 - 1581. Retrieved 2016/06/14.
• 2、 Li, Zhenhuan,Qin, Zhangfeng,Zhu, Huaqing,Wang, Jianguo. "Synthesis of diphenyl carbonate from CO2, phenoxide, and CCl4 with ZnCl2 as catalyst". . p. 784 - 785. Retrieved 2007/10/03.