Carbonic acid benzyl ester (2R,3S)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranylmethyl ester

Base Information

Chemical Name:Carbonic acid benzyl ester (2R,3S)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranylmethyl ester
CAS No.:80532-43-0
Molecular Formula:C₁₆H₂₀O₆
Molecular Weight:308.331
Hs Code.:

Synonyms:Carbonic acid benzyl ester (2R,3S)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranylmethyl ester

Suppliers and Price of Carbonic acid benzyl ester (2R,3S)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranylmethyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Carbonic acid benzyl ester (2R,3S)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranylmethyl ester

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of Carbonic acid benzyl ester (2R,3S)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranylmethyl ester

There total 4 articles about Carbonic acid benzyl ester (2R,3S)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 79060-23-4
(2E)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-en-1-ol

: 80532-43-0
Carbonic acid benzyl ester (2R,3S)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranylmethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: t-BuOOH, Ti(i-PrO)4, (-)-DET / CH₂Cl₂ / 48 h / -23 °C

2: tetrahydrofuran; pyridine / -23 deg C to room temperature

With titanium(IV) isopropylate; tert.-butylhydroperoxide; (-)-diethyl tartrate; In tetrahydrofuran; pyridine; dichloromethane;
DOI:10.1021/ja00368a040

Reference yield:

: 64520-58-7,917877-01-1
ethyl (E)-3-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)acrylate

: 80532-43-0
Carbonic acid benzyl ester (2R,3S)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranylmethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: DIBAL / hexane / -78 °C

2: t-BuOOH, Ti(i-PrO)4, (-)-DET / CH₂Cl₂ / 48 h / -23 °C

3: tetrahydrofuran; pyridine / -23 deg C to room temperature

With titanium(IV) isopropylate; tert.-butylhydroperoxide; diisobutylaluminium hydride; (-)-diethyl tartrate; In tetrahydrofuran; pyridine; hexane; dichloromethane;
DOI:10.1021/ja00368a040

Reference yield:

: 15186-48-8
2,3-isopropylidene-glyceraldehyde

: 80532-43-0
Carbonic acid benzyl ester (2R,3S)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranylmethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: t-BuOK / tetrahydrofuran / -78 °C

2: DIBAL / hexane / -78 °C

3: t-BuOOH, Ti(i-PrO)4, (-)-DET / CH₂Cl₂ / 48 h / -23 °C

4: tetrahydrofuran; pyridine / -23 deg C to room temperature

With titanium(IV) isopropylate; tert.-butylhydroperoxide; potassium tert-butylate; diisobutylaluminium hydride; (-)-diethyl tartrate; In tetrahydrofuran; pyridine; hexane; dichloromethane;
DOI:10.1021/ja00368a040