((2R,4aR,6S,7R,8aR,9R,9aS,10aR)-6-Acetoxy-9-hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester

Base Information

Chemical Name:((2R,4aR,6S,7R,8aR,9R,9aS,10aR)-6-Acetoxy-9-hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester
CAS No.:181263-05-8
Molecular Formula:C₂₁H₂₆O₉
Molecular Weight:422.432
Hs Code.:

Synonyms:((2R,4aR,6S,7R,8aR,9R,9aS,10aR)-6-Acetoxy-9-hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester

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Chemical Property of ((2R,4aR,6S,7R,8aR,9R,9aS,10aR)-6-Acetoxy-9-hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester

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Technology Process of ((2R,4aR,6S,7R,8aR,9R,9aS,10aR)-6-Acetoxy-9-hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester

There total 10 articles about ((2R,4aR,6S,7R,8aR,9R,9aS,10aR)-6-Acetoxy-9-hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 82659-53-8
(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-1-propene

: 181263-05-8
((2R,4aR,6S,7R,8aR,9R,9aS,10aR)-6-Acetoxy-9-hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester

Guidance literature:: Multi-step reaction with 9 steps

1: K₂CO₃ / methanol / 12 h / 23 °C

2: CSA / dimethylformamide / 2 h / 50 °C

3: 90 percent / AgNO₃, pyridine / dimethylformamide / 4 h / 23 °C

4: OsO₄, NMO / 2-methyl-propan-2-ol; tetrahydrofuran; H₂O

5: NaIO₄ / methanol

6: NiCl₂/CrCl₂ / tetrahydrofuran; dimethylsulfoxide / 23 °C

7: 91 percent / pyridine

8: n-Bu₄NF, imidazole / tetrahydrofuran

9: DBU / CH₂Cl₂

With pyridine; 1H-imidazole; chromium dichloride; sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; potassium carbonate; silver nitrate; 1,8-diazabicyclo[5.4.0]undec-7-ene; nickel dichloride; In tetrahydrofuran; methanol; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1021/ja961230+

Reference yield:

: 106756-74-5
(2R,3R,4R,5S,6R)-2-allyl-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol

: 181263-05-8
((2R,4aR,6S,7R,8aR,9R,9aS,10aR)-6-Acetoxy-9-hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: CSA / dimethylformamide / 2 h / 50 °C

2: 90 percent / AgNO₃, pyridine / dimethylformamide / 4 h / 23 °C

3: OsO₄, NMO / 2-methyl-propan-2-ol; tetrahydrofuran; H₂O

4: NaIO₄ / methanol

5: NiCl₂/CrCl₂ / tetrahydrofuran; dimethylsulfoxide / 23 °C

6: 91 percent / pyridine

7: n-Bu₄NF, imidazole / tetrahydrofuran

8: DBU / CH₂Cl₂

With pyridine; 1H-imidazole; chromium dichloride; sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; silver nitrate; 1,8-diazabicyclo[5.4.0]undec-7-ene; nickel dichloride; In tetrahydrofuran; methanol; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1021/ja961230+

Reference yield:

: 181267-07-2
(2R,4aR,6R,7R,8R,8aS)-6-Allyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

: 181263-05-8
((2R,4aR,6S,7R,8aR,9R,9aS,10aR)-6-Acetoxy-9-hydroxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 90 percent / AgNO₃, pyridine / dimethylformamide / 4 h / 23 °C

2: OsO₄, NMO / 2-methyl-propan-2-ol; tetrahydrofuran; H₂O

3: NaIO₄ / methanol

4: NiCl₂/CrCl₂ / tetrahydrofuran; dimethylsulfoxide / 23 °C

5: 91 percent / pyridine

6: n-Bu₄NF, imidazole / tetrahydrofuran

7: DBU / CH₂Cl₂

With pyridine; 1H-imidazole; chromium dichloride; sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; tetrabutyl ammonium fluoride; silver nitrate; 1,8-diazabicyclo[5.4.0]undec-7-ene; nickel dichloride; In tetrahydrofuran; methanol; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1021/ja961230+