C₂₃H₂₈OSSi

Base Information

• Chemical Name: C₂₃H₂₈OSSi
• CAS No.: 1379771-73-9
• Molecular Formula: C₂₃H₂₈OSSi
• Molecular Weight: 380.626
• Mol file: 1379771-73-9.mol

Synonyms:C₂₃H₂₈OSSi

Chemical Property of C₂₃H₂₈OSSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of C₂₃H₂₈OSSi

There total 2 articles about C₂₃H₂₈OSSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

2-benzyloxy(diisopropyl)silyl-5-bromothiophene (1379771-69-3) + Diisopropylphenylsilanol (18052-53-4) → C23H28OSSi (1379771-73-9)

Guidance literature:

With bis(η3-allyl-μ-chloropalladium(II)); triphenyl-arsane; caesium carbonate; In 1,4-dioxane; water; at 90 ℃; for 12h; Inert atmosphere;

DOI:10.1016/j.tetlet.2012.04.059

Reference yield:

2-benzyloxy(diisopropyl)silyl-thiophene (1379771-64-8) → C23H28OSSi (1379771-73-9)

Guidance literature:

Multi-step reaction with 2 steps

1: N-Bromosuccinimide; potassium carbonate / dichloromethane / 4 h / 20 °C / Inert atmosphere

2: bis(η3-allyl-μ-chloropalladium(II)); triphenyl-arsane; caesium carbonate / 1,4-dioxane; water / 12 h / 90 °C / Inert atmosphere

With N-Bromosuccinimide; bis(η3-allyl-μ-chloropalladium(II)); triphenyl-arsane; potassium carbonate; caesium carbonate; In 1,4-dioxane; dichloromethane; water;

DOI:10.1016/j.tetlet.2012.04.059

upstream raw materials:

2-benzyloxy(diisopropyl)silyl-5-bromothiophene

Diisopropylphenylsilanol

2-benzyloxy(diisopropyl)silyl-thiophene