2-amino-N,N'-bis(para-trimethylsilylethynylphenyl)anthraquinone diimine

Base Information

• Chemical Name: 2-amino-N,N'-bis(para-trimethylsilylethynylphenyl)anthraquinone diimine
• CAS No.: 1412771-38-0
• Molecular Formula: C₃₆H₃₅N₃Si₂
• Molecular Weight: 565.865
• Mol file: 1412771-38-0.mol

Synonyms:2-amino-N,N'-bis(para-trimethylsilylethynylphenyl)anthraquinone diimine

Chemical Property of 2-amino-N,N'-bis(para-trimethylsilylethynylphenyl)anthraquinone diimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-amino-N,N'-bis(para-trimethylsilylethynylphenyl)anthraquinone diimine

There total 1 articles about 2-amino-N,N'-bis(para-trimethylsilylethynylphenyl)anthraquinone diimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

4-trimethylsilylethynyl aniline (75867-39-9) + 2-aminoanthraquinone (117-79-3) → 2-amino-N,N'-bis(para-trimethylsilylethynylphenyl)anthraquinone diimine (1412771-38-0)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; titanium tetrachloride; In chlorobenzene; Schlenk technique; Inert atmosphere; Heating;

DOI:10.1039/c2cc36768h

Reference yield: 78.0%

2-amino-N,N'-bis(para-trimethylsilylethynylphenyl)anthraquinone diimine (1412771-38-0) → 2-amino-N,N'-bis(para-ethynylphenyl)anthraquinone diimine (1412771-50-6)

Guidance literature:

With potassium carbonate; In tetrahydrofuran; methanol; Schlenk technique; Inert atmosphere;

DOI:10.1039/c2cc36768h

Reference yield:

2-amino-N,N'-bis(para-trimethylsilylethynylphenyl)anthraquinone diimine (1412771-38-0) → dichloro-2-amino-N,N'-(bis(para-ethynylphenyl)anthraquinonediimine)di-transbis(tributylphosphine)platinum(II)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium carbonate / methanol; tetrahydrofuran / Schlenk technique; Inert atmosphere

2: copper(l) iodide; diisopropylamine / dichloromethane / Schlenk technique; Inert atmosphere

With copper(l) iodide; potassium carbonate; diisopropylamine; In tetrahydrofuran; methanol; dichloromethane;

DOI:10.1039/c2cc36768h

upstream raw materials:

4-trimethylsilylethynyl aniline

2-aminoanthraquinone

Downstream raw materials:

2-amino-N,N'-bis(para-ethynylphenyl)anthraquinone diimine