4-pentenyl O-(4-O-acetyl-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

Base Information

Chemical Name:4-pentenyl O-(4-O-acetyl-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside
CAS No.:199115-83-8
Molecular Formula:C₆₃H₆₂N₂O₁₄
Molecular Weight:1071.19
Hs Code.:

Synonyms:4-pentenyl O-(4-O-acetyl-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

Suppliers and Price of 4-pentenyl O-(4-O-acetyl-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-pentenyl O-(4-O-acetyl-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-pentenyl O-(4-O-acetyl-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

There total 8 articles about 4-pentenyl O-(4-O-acetyl-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.9%

: 108-24-7
acetic anhydride

: 261929-46-8
C₆₁H₆₀N₂O₁₃

: 199115-83-8
4-pentenyl O-(4-O-acetyl-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: With pyridine; at 20 ℃;
DOI:10.1246/bcsj.73.163

Reference yield:

: N-[(2R,3R,4R,5S,6R)-5-((2S,3R,4R,5S,6R)-3-Acetylamino-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-4-hydroxy-6-hydroxymethyl-2-pent-4-enyloxy-tetrahydro-pyran-3-yl]-acetamide

: 199115-83-8
4-pentenyl O-(4-O-acetyl-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: (+)-10-camphorsulfonic acid / dimethylformamide / 28 h / 20 °C / 18.75 Torr

2: aq. NaOH / ethanol / 48 h / 100 °C

3: 3.55 g / triethylamine / methanol; dimethylformamide / 39.5 h / 20 - 120 °C

4: 72.1 percent / n-Bu₄NI; sodium hydride / dimethylformamide / 5.5 h / 20 °C

5: 92.2 percent / sodium cyanotrihydroborate; hydrogen chloride; molecular sieves 4A / tetrahydrofuran; diethyl ether / 0.25 h / 0 °C

6: 97.9 percent / pyridine / 20 °C

With pyridine; hydrogenchloride; sodium hydroxide; 4 A molecular sieve; tetra-(n-butyl)ammonium iodide; sodium hydride; sodium cyanoborohydride; (+)-10-camphorsulfonic acid; triethylamine; In tetrahydrofuran; methanol; diethyl ether; ethanol; N,N-dimethyl-formamide; 1: acetalization / 2: Deacetylation / 3: Acylation / 4: Alkylation / 5: Reduction / 6: Acetylation;
DOI:10.1246/bcsj.73.163

Reference yield:

: 199115-81-6
4-pentenyl O-(4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-2-deoxy-2-phthalimido-β-D-glucopyranoside

: 199115-83-8
4-pentenyl O-(4-O-acetyl-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 72.1 percent / n-Bu₄NI; sodium hydride / dimethylformamide / 5.5 h / 20 °C

2: 92.2 percent / sodium cyanotrihydroborate; hydrogen chloride; molecular sieves 4A / tetrahydrofuran; diethyl ether / 0.25 h / 0 °C

3: 97.9 percent / pyridine / 20 °C

With pyridine; hydrogenchloride; 4 A molecular sieve; tetra-(n-butyl)ammonium iodide; sodium hydride; sodium cyanoborohydride; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; 1: Alkylation / 2: Reduction / 3: Acetylation;
DOI:10.1246/bcsj.73.163