(4R,5S,6S,7S,8R,10S,11S,12R,13S,14R)-15-((R)-4-benzyl-2-oxooxazolidin-3-yl)-5,7,11,13-tetramethoxy-4,6,8,10,12,14-hexamethyl-15-oxopentadec-1-en-3-yl 4-nitrobenzoate

Base Information

Chemical Name:(4R,5S,6S,7S,8R,10S,11S,12R,13S,14R)-15-((R)-4-benzyl-2-oxooxazolidin-3-yl)-5,7,11,13-tetramethoxy-4,6,8,10,12,14-hexamethyl-15-oxopentadec-1-en-3-yl 4-nitrobenzoate
CAS No.:1285480-12-7
Molecular Formula:C₄₂H₆₀N₂O₁₁
Molecular Weight:768.945
Hs Code.:

(4R,5S,6S,7S,8R,10S,11S,12R,13S,14R)-15-((R)-4-benzyl-2-oxooxazolidin-3-yl)-5,7,11,13-tetramethoxy-4,6,8,10,12,14-hexamethyl-15-oxopentadec-1-en-3-yl 4-nitrobenzoate

Synonyms:(4R,5S,6S,7S,8R,10S,11S,12R,13S,14R)-15-((R)-4-benzyl-2-oxooxazolidin-3-yl)-5,7,11,13-tetramethoxy-4,6,8,10,12,14-hexamethyl-15-oxopentadec-1-en-3-yl 4-nitrobenzoate

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Chemical Property of (4R,5S,6S,7S,8R,10S,11S,12R,13S,14R)-15-((R)-4-benzyl-2-oxooxazolidin-3-yl)-5,7,11,13-tetramethoxy-4,6,8,10,12,14-hexamethyl-15-oxopentadec-1-en-3-yl 4-nitrobenzoate

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Technology Process of (4R,5S,6S,7S,8R,10S,11S,12R,13S,14R)-15-((R)-4-benzyl-2-oxooxazolidin-3-yl)-5,7,11,13-tetramethoxy-4,6,8,10,12,14-hexamethyl-15-oxopentadec-1-en-3-yl 4-nitrobenzoate

There total 1 articles about (4R,5S,6S,7S,8R,10S,11S,12R,13S,14R)-15-((R)-4-benzyl-2-oxooxazolidin-3-yl)-5,7,11,13-tetramethoxy-4,6,8,10,12,14-hexamethyl-15-oxopentadec-1-en-3-yl 4-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 1285480-07-0
(R)-4-benzyl-3-((2R,3S,4R,5S,6S,8R,9S,10R,11S,12S)-3,5,9,11-tetramethoxy-2,4,6,8,10,12-hexamethylpentadec-14-enoyl)oxazolidin-2-one

: 62-23-7
4-nitro-benzoic acid

: 1285480-12-7
(4R,5S,6S,7S,8R,10S,11S,12R,13S,14R)-15-((R)-4-benzyl-2-oxooxazolidin-3-yl)-5,7,11,13-tetramethoxy-4,6,8,10,12,14-hexamethyl-15-oxopentadec-1-en-3-yl 4-nitrobenzoate

Guidance literature:: With [1,2-bis-(phenylsulfinyl)ethane]palladium(II) acetate; p-benzoquinone; In 1,4-dioxane; at 45 ℃; for 72h; optical yield given as %de; Inert atmosphere;
DOI:10.1002/anie.201007309

Reference yield:

: 1285480-12-7
(4R,5S,6S,7S,8R,10S,11S,12R,13S,14R)-15-((R)-4-benzyl-2-oxooxazolidin-3-yl)-5,7,11,13-tetramethoxy-4,6,8,10,12,14-hexamethyl-15-oxopentadec-1-en-3-yl 4-nitrobenzoate

: C₃₂H₅₁NO₁₀

Guidance literature:: With dihydrogen peroxide; lithium hydroxide; In tetrahydrofuran; water; at 0 ℃; Inert atmosphere;
DOI:10.1002/anie.201007309