Technology Process of C40H64O7Si2
There total 9 articles about C40H64O7Si2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C47H72O6Si2;
In
tetrahydrofuran;
With
2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium chlorite;
In
acetonitrile;
pH=7;
aq. buffer;
DOI:10.1073/pnas.1015270108
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: 2,6-dimethylpyridine / dichloromethane
2.1: lithium diisopropyl amide / tetrahydrofuran / -78 °C
3.1: dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium; hydrogen / ethanol / 35 - 40 °C / 58505.9 Torr
4.1: lithium borohydride / tetrahydrofuran
5.1: pyridinium p-toluenesulfonate / N,N-dimethyl-formamide
6.1: lithium naphthalenide / tetrahydrofuran
6.2: pH 7 / aq. buffer
With
2,6-dimethylpyridine; lithium borohydride; dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium; hydrogen; pyridinium p-toluenesulfonate; lithium diisopropyl amide;
In
tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1073/pnas.1015270108
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: acetic acid; tetramethylammonium triacetoxyborohydride / acetonitrile / -15 °C
2.1: (+/-)-CSA / toluene / Reflux
3.1: 2,6-dimethylpyridine / dichloromethane
4.1: lithium diisopropyl amide / tetrahydrofuran / -78 °C
5.1: dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium; hydrogen / ethanol / 35 - 40 °C / 58505.9 Torr
6.1: lithium borohydride / tetrahydrofuran
7.1: pyridinium p-toluenesulfonate / N,N-dimethyl-formamide
8.1: lithium naphthalenide / tetrahydrofuran
8.2: pH 7 / aq. buffer
With
2,6-dimethylpyridine; lithium borohydride; dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium; hydrogen; pyridinium p-toluenesulfonate; acetic acid; tetramethylammonium triacetoxyborohydride; lithium diisopropyl amide;
In
tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1073/pnas.1015270108
