1-(N-benzylhydroxylamino)-2,3,5-tri-O-benzyl-1-deoxy-D-ribose

Base Information

Chemical Name:1-(N-benzylhydroxylamino)-2,3,5-tri-O-benzyl-1-deoxy-D-ribose
CAS No.:474799-79-6
Molecular Formula:C₃₃H₃₅NO₅
Molecular Weight:525.645
Hs Code.:

Synonyms:1-(N-benzylhydroxylamino)-2,3,5-tri-O-benzyl-1-deoxy-D-ribose

Suppliers and Price of 1-(N-benzylhydroxylamino)-2,3,5-tri-O-benzyl-1-deoxy-D-ribose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-(N-benzylhydroxylamino)-2,3,5-tri-O-benzyl-1-deoxy-D-ribose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-(N-benzylhydroxylamino)-2,3,5-tri-O-benzyl-1-deoxy-D-ribose

There total 1 articles about 1-(N-benzylhydroxylamino)-2,3,5-tri-O-benzyl-1-deoxy-D-ribose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 16838-89-4
2,3,5-tri-O-benzyl-D-ribofuranose

: 622-30-0
N-benzyl hydroxylalmine

: 474799-79-6
1-(N-benzylhydroxylamino)-2,3,5-tri-O-benzyl-1-deoxy-D-ribose

Guidance literature:: at 110 ℃; for 0.5h;
DOI:10.1021/jo020252d

Reference yield: 72.0%

: 3034-53-5,215777-74-5
2-bromo-1,3-thiazole

: 474799-79-6
1-(N-benzylhydroxylamino)-2,3,5-tri-O-benzyl-1-deoxy-D-ribose

: 474799-80-9
(1R,2S,3R,4R)-1-N-benzylhydroxylamino-2,3,5-tribenzyloxy-1-(1,3-thiazol-2-yl)-4-pentanol

Guidance literature:: 2-bromo-1,3-thiazole; With n-butyllithium; In diethyl ether; hexane; at -78 - -70 ℃;

1-(N-benzylhydroxylamino)-2,3,5-tri-O-benzyl-1-deoxy-D-ribose; In tetrahydrofuran; diethyl ether; hexane; at -70 ℃; for 5h; Further stages.;
DOI:10.1021/jo020252d

Reference yield:

: 474799-79-6
1-(N-benzylhydroxylamino)-2,3,5-tri-O-benzyl-1-deoxy-D-ribose

: (2S,3R,4S,5S)-1-Benzyl-3,4-bis-benzyloxy-2-benzyloxymethyl-5-[(Z)-2-((3aR,4S,6R,6aR)-6-methoxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-vinyl]-pyrrolidine

Guidance literature:: Multi-step reaction with 5 steps

1.1: n-BuLi / hexane; diethyl ether / -78 - -70 °C

1.2: 72 percent / tetrahydrofuran; diethyl ether; hexane / 5 h / -70 °C

2.1: (AcO)2Cu*H₂O; Zn / acetic acid; H₂O / 0.75 h / 20 - 70 °C

3.1: 68 percent / 4 Angstroem molecular sieves; pyridine; Tf₂O / 0.5 h / 40 °C

4.1: 4 Angstroem molecular sieves; methyl triflate / acetonitrile / 0.5 h

4.2: NaBH₄ / methanol / 0.17 h / 20 °C

4.3: AgNO₃ / acetonitrile; H₂O / 0.17 h / 20 °C

5.1: 4 Angstroem molecular sieves; n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / 2 h / -50 °C

With pyridine; n-butyllithium; trifluoromethylsulfonic anhydride; 4 A molecular sieve; copper diacetate; methyl trifluoromethanesulfonate; zinc; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; hexane; water; acetic acid; acetonitrile; 5.1: Wittig reaction;
DOI:10.1021/jo020252d