1,5-anhydro-3-O-benzoyl-2-deoxy-4,6-O-di(tert-butyl)silanediyl-D-arabino-hex-1-enitol

Base Information

Chemical Name:1,5-anhydro-3-O-benzoyl-2-deoxy-4,6-O-di(tert-butyl)silanediyl-D-arabino-hex-1-enitol
CAS No.:310888-64-3
Molecular Formula:C₂₁H₃₀O₅Si
Molecular Weight:390.552
Hs Code.:

Synonyms:1,5-anhydro-3-O-benzoyl-2-deoxy-4,6-O-di(tert-butyl)silanediyl-D-arabino-hex-1-enitol

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Chemical Property of 1,5-anhydro-3-O-benzoyl-2-deoxy-4,6-O-di(tert-butyl)silanediyl-D-arabino-hex-1-enitol

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Technology Process of 1,5-anhydro-3-O-benzoyl-2-deoxy-4,6-O-di(tert-butyl)silanediyl-D-arabino-hex-1-enitol

There total 1 articles about 1,5-anhydro-3-O-benzoyl-2-deoxy-4,6-O-di(tert-butyl)silanediyl-D-arabino-hex-1-enitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 65-85-0,8013-63-6
benzoic acid

: 191593-14-3
4,6-O-di(tert-butyl)silanediyl-D-glucal

: 310888-64-3
1,5-anhydro-3-O-benzoyl-2-deoxy-4,6-O-di(tert-butyl)silanediyl-D-arabino-hex-1-enitol

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃;
DOI:10.1016/S0040-4039(00)01303-4

Reference yield:

: 310888-64-3
1,5-anhydro-3-O-benzoyl-2-deoxy-4,6-O-di(tert-butyl)silanediyl-D-arabino-hex-1-enitol

: 654647-67-3
1,5-anhydro-2-deoxy-3-O-(1-phenyletenyl)-4,6-O-di(tert-butyl)silanediyl-D-arabino-hex-1-enitol

Guidance literature:: With pyridine; In tetrahydrofuran; at -40 ℃; for 1.5h;
DOI:10.1039/b306675b

Reference yield:

: 310888-64-3
1,5-anhydro-3-O-benzoyl-2-deoxy-4,6-O-di(tert-butyl)silanediyl-D-arabino-hex-1-enitol

: 1-(1',5'-anhydro-4',6'-O-di(tert-butyl)silanediyl-2',3'-dideoxy-β-D-erythro-hex-2'-enopyranosyl)acetophenone

Guidance literature:: Multi-step reaction with 2 steps

1: 52 mg / pyridine / tetrahydrofuran / 1.5 h / -40 °C

2: 42 mg / benzonitrile / 0.42 h / 180 °C

With pyridine; In tetrahydrofuran; benzonitrile; 1: Tebbe methylenation / 2: Claisen rearrangement;
DOI:10.1039/b306675b