Tri-O-benzyl-1,2-O-carbonyl-4,6,8,10,11-pentadeoxy-6-(1''-methoxymethoxymethyl)-2,4,8,10-tetra-C-methyl-L-altro-L-galacto-10-eno-undecitol

Base Information

Chemical Name:Tri-O-benzyl-1,2-O-carbonyl-4,6,8,10,11-pentadeoxy-6-(1''-methoxymethoxymethyl)-2,4,8,10-tetra-C-methyl-L-altro-L-galacto-10-eno-undecitol
CAS No.:123506-09-2
Molecular Formula:C₄₀H₅₂O₉
Molecular Weight:676.847
Hs Code.:

Synonyms:Tri-O-benzyl-1,2-O-carbonyl-4,6,8,10,11-pentadeoxy-6-(1''-methoxymethoxymethyl)-2,4,8,10-tetra-C-methyl-L-altro-L-galacto-10-eno-undecitol

Suppliers and Price of Tri-O-benzyl-1,2-O-carbonyl-4,6,8,10,11-pentadeoxy-6-(1''-methoxymethoxymethyl)-2,4,8,10-tetra-C-methyl-L-altro-L-galacto-10-eno-undecitol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Tri-O-benzyl-1,2-O-carbonyl-4,6,8,10,11-pentadeoxy-6-(1''-methoxymethoxymethyl)-2,4,8,10-tetra-C-methyl-L-altro-L-galacto-10-eno-undecitol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Tri-O-benzyl-1,2-O-carbonyl-4,6,8,10,11-pentadeoxy-6-(1''-methoxymethoxymethyl)-2,4,8,10-tetra-C-methyl-L-altro-L-galacto-10-eno-undecitol

There total 26 articles about Tri-O-benzyl-1,2-O-carbonyl-4,6,8,10,11-pentadeoxy-6-(1''-methoxymethoxymethyl)-2,4,8,10-tetra-C-methyl-L-altro-L-galacto-10-eno-undecitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 123506-08-1
(S)-4-[(1R,2S,3S,4R)-1,3-Bis-benzyloxy-4-((3S,4R,5R)-4-benzyloxy-5-bromomethyl-3,5-dimethyl-tetrahydro-furan-2-yl)-2-iodomethyl-5-methoxymethoxy-pentyl]-4-methyl-[1,3]dioxolan-2-one

: 123506-09-2
Tri-O-benzyl-1,2-O-carbonyl-4,6,8,10,11-pentadeoxy-6-(1''-methoxymethoxymethyl)-2,4,8,10-tetra-C-methyl-L-altro-L-galacto-10-eno-undecitol

Guidance literature:: With ammonium chloride; zinc; In ethanol; Heating;
DOI:10.1021/jo00284a030

Reference yield: 92.0%

: 123506-08-1
(S)-4-[(1S,2S,3S,4R)-1,3-Bis-benzyloxy-4-((2R,3S,4R,5S)-4-benzyloxy-5-bromomethyl-3,5-dimethyl-tetrahydro-furan-2-yl)-2-iodomethyl-5-methoxymethoxy-pentyl]-4-methyl-[1,3]dioxolan-2-one

: 123506-09-2
Tri-O-benzyl-1,2-O-carbonyl-4,6,8,10,11-pentadeoxy-6-(1''-methoxymethoxymethyl)-2,4,8,10-tetra-C-methyl-L-altro-L-galacto-10-eno-undecitol

Guidance literature:: With amalgamated zinc; ammonium chloride; In ethanol; for 20h; Heating;
DOI:10.1016/S0040-4020(01)97592-1

Reference yield:

: 123505-99-7
(2S,3R,4S,4aS,5S,6S,8aS)-4,5-Bis-benzyloxy-2-isopropenyl-6-(4-methoxy-benzyloxy)-3-methoxymethoxymethyl-6-methyl-hexahydro-pyrano[2,3-b]pyran

: 123506-09-2
Tri-O-benzyl-1,2-O-carbonyl-4,6,8,10,11-pentadeoxy-6-(1''-methoxymethoxymethyl)-2,4,8,10-tetra-C-methyl-L-altro-L-galacto-10-eno-undecitol

Guidance literature:: Multi-step reaction with 10 steps

1: 1.) 9-BBN, 2.) Na₂O₂ / 1.) THF

2: PCC, Celite, Fluorisil, NaOAC / CH₂Cl₂

3: tetrahydrofuran / -90 °C

4: 1.) NaH, 2.) n-Bu₄NI / 1.) DMF

5: 86 percent / NBS, NaHCO₃ / acetonitrile

6: 1.) Swern's oxid. / 2.) CH₂Cl₂

7: 1.) DDQ, MS 4A, 2.) LAH / 1.) CH₂Cl₂, 2.) ether

8: 1.) NaBH₄, 2.) pyridine / 1.) EtOH, 2.) CH₂Cl₂

9: 80 percent / I₂, Ph₃P, imidazole / benzene

10: 92 percent / Zn, NH₄Cl / ethanol / Heating

With pyridine; 1H-imidazole; sodium tetrahydroborate; N-Bromosuccinimide; lithium aluminium tetrahydride; 9-borabicyclo[3.3.1]nonane dimer; sodium peroxide; Florisil; Celite; Swern's oxid; iodine; sodium acetate; tetra-(n-butyl)ammonium iodide; sodium hydride; sodium hydrogencarbonate; ammonium chloride; triphenylphosphine; pyridinium chlorochromate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; zinc; In tetrahydrofuran; ethanol; dichloromethane; acetonitrile; benzene;
DOI:10.1021/jo00284a030