allyl 2-<(3S,4S)-4-(hydroxymethyl)-2-oxo-3-tritylamino-1-azetidinyl>-3-oxopropanoate

Base Information

Chemical Name:allyl 2-<(3S,4S)-4-(hydroxymethyl)-2-oxo-3-tritylamino-1-azetidinyl>-3-oxopropanoate
CAS No.:113599-73-8
Molecular Formula:C₂₉H₂₈N₂O₅
Molecular Weight:484.552
Hs Code.:

Synonyms:allyl 2-<(3S,4S)-4-(hydroxymethyl)-2-oxo-3-tritylamino-1-azetidinyl>-3-oxopropanoate

Suppliers and Price of allyl 2-<(3S,4S)-4-(hydroxymethyl)-2-oxo-3-tritylamino-1-azetidinyl>-3-oxopropanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of allyl 2-<(3S,4S)-4-(hydroxymethyl)-2-oxo-3-tritylamino-1-azetidinyl>-3-oxopropanoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of allyl 2-<(3S,4S)-4-(hydroxymethyl)-2-oxo-3-tritylamino-1-azetidinyl>-3-oxopropanoate

There total 5 articles about allyl 2-<(3S,4S)-4-(hydroxymethyl)-2-oxo-3-tritylamino-1-azetidinyl>-3-oxopropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 113599-66-9
allyl 2-<(3S,4S)-4-<<(tert-butyldimethylsilyl)oxy>methyl>-2-oxo-3-tritylamino-1-azetidinyl>-3-oxopropanoate

: 113599-73-8
allyl 2-<(3S,4S)-4-(hydroxymethyl)-2-oxo-3-tritylamino-1-azetidinyl>-3-oxopropanoate

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran;
DOI:10.1021/jm00401a020

Reference yield:

: 40630-84-0
allyl bromoacetate

: 113599-73-8
allyl 2-<(3S,4S)-4-(hydroxymethyl)-2-oxo-3-tritylamino-1-azetidinyl>-3-oxopropanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 59 percent / tetrabutylammonium bromide, KOH / tetrahydrofuran / 20 h

2: 86 percent / lithium bis(trimethylsilyl)amide / tetrahydrofuran / -78 °C

3: 89 percent / tetrabutylammonium fluoride / tetrahydrofuran

With potassium hydroxide; tetrabutyl ammonium fluoride; tetrabutylammomium bromide; lithium hexamethyldisilazane; In tetrahydrofuran;
DOI:10.1021/jm00401a020

Reference yield:

: 76-83-5
trityl chloride

: 113599-73-8
allyl 2-<(3S,4S)-4-(hydroxymethyl)-2-oxo-3-tritylamino-1-azetidinyl>-3-oxopropanoate

Guidance literature:: Multi-step reaction with 4 steps

1: NEt₃ / CH₂Cl₂ / 1.5 h

2: 59 percent / tetrabutylammonium bromide, KOH / tetrahydrofuran / 20 h

3: 86 percent / lithium bis(trimethylsilyl)amide / tetrahydrofuran / -78 °C

4: 89 percent / tetrabutylammonium fluoride / tetrahydrofuran

With potassium hydroxide; tetrabutyl ammonium fluoride; tetrabutylammomium bromide; triethylamine; lithium hexamethyldisilazane; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jm00401a020