{CpFeCO{P(OC6H5)3}(η1-(Z)-C(Ph)=C(Ph)Me)}

Base Information

Chemical Name:{CpFeCO{P(OC6H5)3}(η1-(Z)-C(Ph)=C(Ph)Me)}
CAS No.:101052-83-9
Molecular Formula:C₃₉H₃₃FeO₄P
Molecular Weight:652.509
Hs Code.:

Synonyms:{CpFeCO{P(OC6H5)3}(η1-(Z)-C(Ph)=C(Ph)Me)}

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Chemical Property of {CpFeCO{P(OC6H5)3}(η1-(Z)-C(Ph)=C(Ph)Me)}

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Technology Process of {CpFeCO{P(OC6H5)3}(η1-(Z)-C(Ph)=C(Ph)Me)}

There total 1 articles about {CpFeCO{P(OC6H5)3}(η1-(Z)-C(Ph)=C(Ph)Me)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 71341-58-7
[C₅H₅FeCO[P(OC₆H₅)3](C₆H₅CCC₆H₅)]⁽¹⁺⁾*BF₄^(1-)=[C₅H₅FeCO[P(OC₆H₅)3](C₆H₅CCC₆H₅)]BF₄

: 80473-70-7
(lithium)2(CN)(methyl)2cuprate

: 101052-83-9
{CpFeCO{P(OC6H5)3}(η1-(Z)-C(Ph)=C(Ph)Me)}

Guidance literature:: In tetrahydrofuran; under N2, cold (-50°C) THF soln. of Me2Cu(CN)Li2 added to cold (-78°C) THF soln. of (CpFeCO(P(OPh)3)(PhC2Ph))BF4, stirred at -78°C for 10 min and addnl. 50 min without cooling; evapd., redissolved in CH2Cl2, filtered through Al2O3 plug, evapd., dissolved in C6H6, chromd. (Al2O3, 50% C6H6/hexane), evapd.; elem. anal.;
DOI:10.1021/ja00268a036

Reference yield: 84.0%

: 101052-83-9
{CpFeCO{P(OC6H5)3}(η1-(Z)-C(Ph)=C(Ph)Me)}

: C₅H₅FeCO[P(OC₆H₅)3](C(O)C(C₆H₅)C(C₆H₅)CH₃)

Guidance literature:: With CO; ammonium cerium (IV) nitrate; In ethanol; dichloromethane; Fe-complex in CH2Cl2 and (NH4)2Ce(NO3)6 in EtOH separately cooled to -78°C under CO (1 atm) with vigorous stirring for 30 min, 2nd soln.added to 1st one under CO, stirred for 30 min at -78°C and 40 min without cooling; evapd., dissolved in CH2Cl2, filtered through Al2O3 plug, evapd., dissolved in C6H6, chromd. (Al2O3, 50% C6H6/hexane, 100% C6H6, 100% CH2Cl2); elem. anal.;
DOI:10.1021/ja00268a036