C₅₂H₉₃N₃O₁₂Si₃

Base Information

Chemical Name:C₅₂H₉₃N₃O₁₂Si₃
CAS No.:444687-43-8
Molecular Formula:C₅₂H₉₃N₃O₁₂Si₃
Molecular Weight:1036.58
Hs Code.:

C<sub>52</sub>H<sub>93</sub>N<sub>3</sub>O<sub>12</sub>Si<sub>3</sub>

Synonyms:C₅₂H₉₃N₃O₁₂Si₃

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Chemical Property of C₅₂H₉₃N₃O₁₂Si₃

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Technology Process of C₅₂H₉₃N₃O₁₂Si₃

There total 17 articles about C₅₂H₉₃N₃O₁₂Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 98894-85-0
(Z)-6-chlorohex-2-en-1-ol tert-butyldimethylsilyl ether

: 444687-43-8
C₅₂H₉₃N₃O₁₂Si₃

Guidance literature:: Multi-step reaction with 15 steps

1.1: magnesium; Br(CH₂)2Br / tetrahydrofuran / 3 h / Heating

1.2: 94 percent / tetrahydrofuran / 3 h / -78 - 20 °C

2.1: 85 percent / oxalyl chloride; DMSO; NEt₃ / CH₂Cl₂ / 6.5 h / -78 - 20 °C

3.1: 94 percent / Zn(BH₄)2; CeCl₃*7H₂O / diethyl ether; methanol / 4 h / 0 °C

4.1: tetrabutylammonium fluoride / tetrahydrofuran / 2 h / 20 °C

5.1: 8.27 g / 2,6-lutidine / CH₂Cl₂ / 1 h / -15 °C

6.1: 96 percent / Pd₂(dba)3*CHCl₃; (S,S)-1,2-di[2'-(diphenylphosphino)benzamido]cyclohexane / tetrahydrofuran; diethyl ether / 12 h / 20 °C

7.1: ozone / CH₂Cl₂ / -78 °C

7.2: triphenylphosphine / CH₂Cl₂ / 4 h / cooling

8.1: 5.47 g / sodium hypochlorite; NaH₂PO₄*H₂O; 2-methyl-2-butene / 2-methyl-propan-2-ol; H₂O / 2 h / 20 °C

9.1: 83 percent / 1,8-diazabicyclo[5.4.0]undec-7-ene / benzene / 18 h / 20 °C

10.1: 98 percent / camphorsulfonic acid / methanol; tetrahydrofuran / 12 h / 50 °C

11.1: 90 percent / imidazole / CH₂Cl₂ / 1 h / 20 °C

12.1: 100 percent / hydrogen / Pd/C / ethyl acetate; methanol / 12 h

13.1: 81 percent / diisopropylcarbodiimide; 1-hydroxybenzotriazole / CH₂Cl₂; dimethylformamide / 24 h / 20 °C

14.1: hydrogen / Pd/C / ethyl acetate; methanol / 12 h

15.1: 0.162 g / diisopropylcarbodiimide; 1-hydroxybenzotriazole / CH₂Cl₂; dimethylformamide / 48 h / 20 °C

With 1H-imidazole; 2,6-dimethylpyridine; trans-1,2-(1S,2S)-1,2-diaminocyclohexane-N,N’-bis(2’-diphenylphosphinobenzoyl); tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium hypochlorite; sodium dihydrogenphosphate; cerium(III) chloride; zinc(II) tetrahydroborate; 2-methyl-but-2-ene; oxalyl dichloride; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; hydrogen; benzotriazol-1-ol; ozone; magnesium; dimethyl sulfoxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; ethylene dibromide; triethylamine; diisopropyl-carbodiimide; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; tert-butyl alcohol; benzene; 1.2: Grignard addition / 2.1: Swern oxidation / 3.1: Luche reduction;
DOI:10.1021/ol0261480

Reference yield:

: 444687-29-0
(S)-2,2-Dimethyl-4-((2R,6S)-6-vinyl-tetrahydro-pyran-2-yl)-oxazolidine-3-carboxylic acid benzyl ester

: 444687-43-8
C₅₂H₉₃N₃O₁₂Si₃

Guidance literature:: Multi-step reaction with 9 steps

1.1: ozone / CH₂Cl₂ / -78 °C

1.2: triphenylphosphine / CH₂Cl₂ / 4 h / cooling

2.1: 5.47 g / sodium hypochlorite; NaH₂PO₄*H₂O; 2-methyl-2-butene / 2-methyl-propan-2-ol; H₂O / 2 h / 20 °C

3.1: 83 percent / 1,8-diazabicyclo[5.4.0]undec-7-ene / benzene / 18 h / 20 °C

4.1: 98 percent / camphorsulfonic acid / methanol; tetrahydrofuran / 12 h / 50 °C

5.1: 90 percent / imidazole / CH₂Cl₂ / 1 h / 20 °C

6.1: 100 percent / hydrogen / Pd/C / ethyl acetate; methanol / 12 h

7.1: 81 percent / diisopropylcarbodiimide; 1-hydroxybenzotriazole / CH₂Cl₂; dimethylformamide / 24 h / 20 °C

8.1: hydrogen / Pd/C / ethyl acetate; methanol / 12 h

9.1: 0.162 g / diisopropylcarbodiimide; 1-hydroxybenzotriazole / CH₂Cl₂; dimethylformamide / 48 h / 20 °C

With 1H-imidazole; sodium hypochlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; camphor-10-sulfonic acid; hydrogen; benzotriazol-1-ol; ozone; 1,8-diazabicyclo[5.4.0]undec-7-ene; diisopropyl-carbodiimide; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; tert-butyl alcohol; benzene;
DOI:10.1021/ol0261480

Reference yield:

: 444687-27-8
(S)-4-((Z)-(R)-7-Acetoxy-1-hydroxy-hept-5-enyl)-2,2-dimethyl-oxazolidine-3-carboxylic acid benzyl ester

: 444687-43-8
C₅₂H₉₃N₃O₁₂Si₃

Guidance literature:: Multi-step reaction with 10 steps

1.1: 96 percent / Pd₂(dba)3*CHCl₃; (S,S)-1,2-di[2'-(diphenylphosphino)benzamido]cyclohexane / tetrahydrofuran; diethyl ether / 12 h / 20 °C

2.1: ozone / CH₂Cl₂ / -78 °C

2.2: triphenylphosphine / CH₂Cl₂ / 4 h / cooling

3.1: 5.47 g / sodium hypochlorite; NaH₂PO₄*H₂O; 2-methyl-2-butene / 2-methyl-propan-2-ol; H₂O / 2 h / 20 °C

4.1: 83 percent / 1,8-diazabicyclo[5.4.0]undec-7-ene / benzene / 18 h / 20 °C

5.1: 98 percent / camphorsulfonic acid / methanol; tetrahydrofuran / 12 h / 50 °C

6.1: 90 percent / imidazole / CH₂Cl₂ / 1 h / 20 °C

7.1: 100 percent / hydrogen / Pd/C / ethyl acetate; methanol / 12 h

8.1: 81 percent / diisopropylcarbodiimide; 1-hydroxybenzotriazole / CH₂Cl₂; dimethylformamide / 24 h / 20 °C

9.1: hydrogen / Pd/C / ethyl acetate; methanol / 12 h

10.1: 0.162 g / diisopropylcarbodiimide; 1-hydroxybenzotriazole / CH₂Cl₂; dimethylformamide / 48 h / 20 °C

With 1H-imidazole; trans-1,2-(1S,2S)-1,2-diaminocyclohexane-N,N’-bis(2’-diphenylphosphinobenzoyl); tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium hypochlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; camphor-10-sulfonic acid; hydrogen; benzotriazol-1-ol; ozone; 1,8-diazabicyclo[5.4.0]undec-7-ene; diisopropyl-carbodiimide; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; tert-butyl alcohol; benzene;
DOI:10.1021/ol0261480