12-{5-(p-(tert-butyl)phenyl)amino-4-[(p-(tert-butyl)phenyl)imino]-4H-imidazol-2-yl}-benzo[k]fluoranthene-7-carbonitrile

Base Information

• Chemical Name: 12-{5-(p-(tert-butyl)phenyl)amino-4-[(p-(tert-butyl)phenyl)imino]-4H-imidazol-2-yl}-benzo[k]fluoranthene-7-carbonitrile
• CAS No.: 1001406-00-3
• Molecular Formula: C₄₄H₃₇N₅
• Molecular Weight: 635.811
• Mol file: 1001406-00-3.mol

Synonyms:12-{5-(p-(tert-butyl)phenyl)amino-4-[(p-(tert-butyl)phenyl)imino]-4H-imidazol-2-yl}-benzo[k]fluoranthene-7-carbonitrile

Chemical Property of 12-{5-(p-(tert-butyl)phenyl)amino-4-[(p-(tert-butyl)phenyl)imino]-4H-imidazol-2-yl}-benzo[k]fluoranthene-7-carbonitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 12-{5-(p-(tert-butyl)phenyl)amino-4-[(p-(tert-butyl)phenyl)imino]-4H-imidazol-2-yl}-benzo[k]fluoranthene-7-carbonitrile

There total 2 articles about 12-{5-(p-(tert-butyl)phenyl)amino-4-[(p-(tert-butyl)phenyl)imino]-4H-imidazol-2-yl}-benzo[k]fluoranthene-7-carbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C9H27NSi3C20H10C2N2 + oxalic acid N,N'-bis(4-tert-butylphenyl)imidoyl dichloride → 12-{5-(p-(tert-butyl)phenyl)amino-4-[(p-(tert-butyl)phenyl)imino]-4H-imidazol-2-yl}-benzo[k]fluoranthene-7-carbonitrile (1001406-00-3)

Guidance literature:

With potassium fluoride; 18-crown-6 ether; In tetrahydrofuran; at 40 - 50 ℃; for 3h;

DOI:10.3390/12040723

Reference yield:

7,12-dicyano-benzofluoranthene (72851-41-3) → 12-{5-(p-(tert-butyl)phenyl)amino-4-[(p-(tert-butyl)phenyl)imino]-4H-imidazol-2-yl}-benzo[k]fluoranthene-7-carbonitrile (1001406-00-3)

Guidance literature:

Multi-step reaction with 2 steps

1.1: tetrahydrofuran / 96 h / 20 °C

1.2: toluene / 12 h / 110 °C

2.1: KF; 18-crown-6-ether / tetrahydrofuran / 3 h / 40 - 50 °C

With potassium fluoride; 18-crown-6 ether; In tetrahydrofuran;

DOI:10.3390/12040723

Reference yield: 48.0%

12-{5-(p-(tert-butyl)phenyl)amino-4-[(p-(tert-butyl)phenyl)imino]-4H-imidazol-2-yl}-benzo[k]fluoranthene-7-carbonitrile (1001406-00-3) → 12-[2,2-difluoro-1,3-bis(4-(tert-butyl)phenyl)-1,2-dihydro-1,3,4,6-tetraaza-2-borapentalen-5-yl]-benzo[k]fluoranthene-7-carbonitrile

Guidance literature:

With boron trifluoride diethyl etherate; triethylamine; In toluene;

DOI:10.3390/12040723

upstream raw materials:

7,12-dicyano-benzofluoranthene