[4,4'-bis(1-benzyl-1H-1,2,3-triazol-4-yl)-2,2'-bipyridine]bis(phenylethynyl)platinum(II)

Base Information

Chemical Name:[4,4'-bis(1-benzyl-1H-1,2,3-triazol-4-yl)-2,2'-bipyridine]bis(phenylethynyl)platinum(II)
CAS No.:1374024-45-9
Molecular Formula:C₄₄H₃₂N₈Pt
Molecular Weight:867.872
Hs Code.:

Synonyms:[4,4'-bis(1-benzyl-1H-1,2,3-triazol-4-yl)-2,2'-bipyridine]bis(phenylethynyl)platinum(II)

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Chemical Property of [4,4'-bis(1-benzyl-1H-1,2,3-triazol-4-yl)-2,2'-bipyridine]bis(phenylethynyl)platinum(II)

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Technology Process of [4,4'-bis(1-benzyl-1H-1,2,3-triazol-4-yl)-2,2'-bipyridine]bis(phenylethynyl)platinum(II)

There total 3 articles about [4,4'-bis(1-benzyl-1H-1,2,3-triazol-4-yl)-2,2'-bipyridine]bis(phenylethynyl)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1374024-43-7
bis(phenylethynyl)[4,4'-bis(trimethylsilylethynyl)-2,2'-bipyridine]platinum(II)

: 622-79-7
benzyl azide

: 1374024-45-9
[4,4'-bis(1-benzyl-1H-1,2,3-triazol-4-yl)-2,2'-bipyridine]bis(phenylethynyl)platinum(II)

Guidance literature:: With KF; ethyldiisopropylamine (DIPEA); Cu; tetrakis(actonitrile)copper(I) hexafluorophosphate; In methanol; dichloromethane; under Ar; KF (0.201 mmol) and MeOH added to Pt complex (0.080 mmol) soln., degassed, Cu(CH3CN)4PF6 (0.024 mmol), DIPEA (0.32 mmol), Cu (0.024 mmol) and N3CH2C6H5 (0.201 mmol) added, stirred (room temp., 2 d), NH4OH soln. and CH2Cl2 added, stirred; layers sepd., aq. layer extracted with CH2Cl2, organic layer washed withNa2/EDTA soln., dried with Na2SO4, solvent removed in vac., residue chr omd. (silica, CH2Cl2/Et2O), dissolved (CH2Cl2), petroleum ether added, ppt. filtered off, washed (PE), dried;
DOI:10.1002/ejic.201200061

Reference yield:

: 133810-43-2
4,4'-bis<2-(trimethylsilyl)-1-ethynyl>-2,2'-bipyridine

: 1374024-45-9
[4,4'-bis(1-benzyl-1H-1,2,3-triazol-4-yl)-2,2'-bipyridine]bis(phenylethynyl)platinum(II)

Guidance literature:: Multi-step reaction with 3 steps

1: acetonitrile

2: diisopropylamine; CuI / dichloromethane

3: KF; ethyldiisopropylamine (DIPEA); Cu / tetrakis(actonitrile)copper(I) hexafluorophosphate / dichloromethane; methanol

With diisopropylamine; CuI; KF; ethyldiisopropylamine (DIPEA); Cu; tetrakis(actonitrile)copper(I) hexafluorophosphate; In methanol; dichloromethane; acetonitrile;
DOI:10.1002/ejic.201200061

Reference yield:

: 1374024-42-6
dichloro[4,4'-bis(trimethylsilylethynyl)-2,2'-bipyridine]platinum(II)

: 1374024-45-9
[4,4'-bis(1-benzyl-1H-1,2,3-triazol-4-yl)-2,2'-bipyridine]bis(phenylethynyl)platinum(II)

Guidance literature:: Multi-step reaction with 2 steps

1: diisopropylamine; CuI / dichloromethane

2: KF; ethyldiisopropylamine (DIPEA); Cu / tetrakis(actonitrile)copper(I) hexafluorophosphate / dichloromethane; methanol

With diisopropylamine; CuI; KF; ethyldiisopropylamine (DIPEA); Cu; tetrakis(actonitrile)copper(I) hexafluorophosphate; In methanol; dichloromethane;
DOI:10.1002/ejic.201200061