C₂₃H₂₇NO₃S

Base Information

• Chemical Name: C₂₃H₂₇NO₃S
• CAS No.: 1174503-11-7
• Molecular Formula: C₂₃H₂₇NO₃S
• Molecular Weight: 397.538
• Mol file: 1174503-11-7.mol

Synonyms:C₂₃H₂₇NO₃S

Chemical Property of C₂₃H₂₇NO₃S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₃H₂₇NO₃S

There total 1 articles about C₂₃H₂₇NO₃S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

N-prenyl-N-propargyltosylamide (132330-44-0) + m-tolyl aldehyde (620-23-5) → C23H27NO3S (1174503-11-7)

Guidance literature:

N-prenyl-N-propargyltosylamide; With ethylmagnesium bromide; In tetrahydrofuran; at 50 ℃; for 1h;

m-tolyl aldehyde; In tetrahydrofuran; at 20 ℃; for 3h;

DOI:10.1016/j.tetlet.2017.11.018

Reference yield: 81.0%

C23H27NO3S (1174503-11-7) → 3-(prop-1-en-2-yl)-4-(2-m-tolylvinylidene)-1-tosylpyrrolidine (1266550-18-8)

Guidance literature:

With trifluorormethanesulfonic acid; In dichloromethane; water; at 0 ℃; for 0.0833333h;

DOI:10.1002/chem.201002222

Reference yield: 73.0%

C23H27NO3S (1174503-11-7) → C23H27NO3S (1174503-30-0)

Guidance literature:

With silver hexafluoroantimonate; In dichloromethane; at 15 ℃; for 14h;

DOI:10.1021/ol901270b

upstream raw materials:

N-prenyl-N-propargyltosylamide

m-tolyl aldehyde

Downstream raw materials:

C₂₃H₂₇NO₃S

3-(prop-1-en-2-yl)-4-(2-m-tolylvinylidene)-1-tosylpyrrolidine

C₂₃H₂₅NO₂S

C₂₅H₂₉NO₅S

Refernces

• 1、 Zhao, Shu-Chun,Ji, Ke-Gong,Lu, Lei,He, Ting,Zhou, An-Xi,Yan, Ru-Long,Ali, Shaukat,Liu, Xue-Yuan,Liang, Yong-Min. "Palladium-catalyzed divergent reactions of 1,6-enyne carbonates: Synthesis of vinylidenepyridines and vinylidenepyrrolidines". experimental part. p. 2763 - 2772. Retrieved 2012/05/05.