C₃₅H₄₂N₂O₅SSi

Base Information

• Chemical Name: C₃₅H₄₂N₂O₅SSi
• CAS No.: 1565836-88-5
• Molecular Formula: C₃₅H₄₂N₂O₅SSi
• Molecular Weight: 630.88
• Mol file: 1565836-88-5.mol

Synonyms:C₃₅H₄₂N₂O₅SSi

Chemical Property of C₃₅H₄₂N₂O₅SSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₅H₄₂N₂O₅SSi

There total 12 articles about C₃₅H₄₂N₂O₅SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

C35H42N2O6Si (1565836-79-4) → C35H42N2O5SSi (1565836-88-5)

Guidance literature:

With Lawessons reagent; In toluene; at 100 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/ja500548e

Reference yield:

C37H48N2O7S2Si (1565836-73-8) → C35H42N2O5SSi (1565836-88-5)

Guidance literature:

Multi-step reaction with 4 steps

1.1: toluene / 36 h / 150 °C

2.1: lithium diisopropyl amide / tetrahydrofuran / 0.5 h / -78 °C

2.2: 2.5 h / -78 °C

3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / -78 - 25 °C

4.1: Lawessons reagent / toluene / 0.5 h / 100 °C / Inert atmosphere

With Lawessons reagent; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; toluene;

DOI:10.1021/ja500548e

Reference yield:

C35H46N2O7Si (1565836-72-7) → C35H42N2O5SSi (1565836-88-5)

Guidance literature:

Multi-step reaction with 5 steps

1.1: 1H-imidazole; sodium hydride / tetrahydrofuran; mineral oil / 0 - 25 °C

1.2: 1 h / 0 - 25 °C

1.3: 1 h / 0 - 25 °C

2.1: toluene / 36 h / 150 °C

3.1: lithium diisopropyl amide / tetrahydrofuran / 0.5 h / -78 °C

3.2: 2.5 h / -78 °C

4.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / -78 - 25 °C

5.1: Lawessons reagent / toluene / 0.5 h / 100 °C / Inert atmosphere

With Lawessons reagent; 1H-imidazole; sodium hydride; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; toluene; mineral oil;

DOI:10.1021/ja500548e

upstream raw materials:

C₃₅H₄₆N₂O₇Si

C₃₇H₄₈N₂O₇S₂Si

C₃₅H₄₂N₂O₆Si

6-(tert-butyldimethylsilyloxy)-4-methylenehexanoic acid

Downstream raw materials:

C₃₅H₄₄N₂O₅Si

C₂₉H₃₀N₂O₅

C₂₉H₂₉IN₂O₄