p-tolyl 3,4,6-tri-O-benzyl-(2,5-difluorobenzoyl)-1-thio-α-D-mannopyranoside

Base Information

Chemical Name:p-tolyl 3,4,6-tri-O-benzyl-(2,5-difluorobenzoyl)-1-thio-α-D-mannopyranoside
CAS No.:1451180-98-5
Molecular Formula:C₄₁H₃₈F₂O₆S
Molecular Weight:696.812
Hs Code.:

Synonyms:p-tolyl 3,4,6-tri-O-benzyl-(2,5-difluorobenzoyl)-1-thio-α-D-mannopyranoside

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Chemical Property of p-tolyl 3,4,6-tri-O-benzyl-(2,5-difluorobenzoyl)-1-thio-α-D-mannopyranoside

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Technology Process of p-tolyl 3,4,6-tri-O-benzyl-(2,5-difluorobenzoyl)-1-thio-α-D-mannopyranoside

There total 1 articles about p-tolyl 3,4,6-tri-O-benzyl-(2,5-difluorobenzoyl)-1-thio-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 35730-09-7
2,5-difluorobenzoyl chloride

: 793672-50-1
4-methylphenyl 3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside

: 1451180-98-5
p-tolyl 3,4,6-tri-O-benzyl-(2,5-difluorobenzoyl)-1-thio-α-D-mannopyranoside

Guidance literature:: With pyridine; dmap; at 20 ℃; Inert atmosphere;
DOI:10.1021/ja405990z

Reference yield: 94.0%

: 1451180-98-5
p-tolyl 3,4,6-tri-O-benzyl-(2,5-difluorobenzoyl)-1-thio-α-D-mannopyranoside

: 1451181-00-2
benzyl [3,4,6-tri-O-benzyl-2-O-(2,5-difluorobenzoyl)-α-D-mannopyranosyl-(1→3)]-2-O-benzyl-β-D-mannopyranosyl-(1→4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

: benzyl [3,4,6-tri-O-benzyl-2-O-(2,5-difluorobenzoyl)-α-D-mannopyranosyl-(1→3)]-[3,4,6-tri-O-benzyl-2-O-(2,5-difluorobenzoyl)-α-D-mannopyranosyl-(1→6)]-2-O-benzyl-β-D-mannopyranosyl-(1→4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: p-tolyl 3,4,6-tri-O-benzyl-(2,5-difluorobenzoyl)-1-thio-α-D-mannopyranoside; benzyl [3,4,6-tri-O-benzyl-2-O-(2,5-difluorobenzoyl)-α-D-mannopyranosyl-(1→3)]-2-O-benzyl-β-D-mannopyranosyl-(1→4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere; Molecular sieve;

With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -40 - 0 ℃; for 5h; Inert atmosphere; Molecular sieve;
DOI:10.1021/ja405990z

Reference yield: 63.0%

: 1400810-12-9
benzyl 2-O-benzyl-4,6-O-(R)-benzylidene-β-D-mannopyranosyl-(1→4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

: 1451180-98-5
p-tolyl 3,4,6-tri-O-benzyl-(2,5-difluorobenzoyl)-1-thio-α-D-mannopyranoside

: 1451181-00-2
benzyl [3,4,6-tri-O-benzyl-2-O-(2,5-difluorobenzoyl)-α-D-mannopyranosyl-(1→3)]-2-O-benzyl-β-D-mannopyranosyl-(1→4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: benzyl 2-O-benzyl-4,6-O-(R)-benzylidene-β-D-mannopyranosyl-(1→4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside; p-tolyl 3,4,6-tri-O-benzyl-(2,5-difluorobenzoyl)-1-thio-α-D-mannopyranoside; With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 0 - 20 ℃; Molecular sieve;

With acetic acid; In water; Molecular sieve;