(1S,2R)-2-tert-butyldiphenylsilyloxy-1-methyl-3-butenyl (S)-3-hydroxybutyrate

Base Information

Chemical Name:(1S,2R)-2-tert-butyldiphenylsilyloxy-1-methyl-3-butenyl (S)-3-hydroxybutyrate
CAS No.:1335286-54-8
Molecular Formula:C₂₅H₃₄O₄Si
Molecular Weight:426.628
Hs Code.:

Synonyms:(1S,2R)-2-tert-butyldiphenylsilyloxy-1-methyl-3-butenyl (S)-3-hydroxybutyrate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,2R)-2-tert-butyldiphenylsilyloxy-1-methyl-3-butenyl (S)-3-hydroxybutyrate

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Technology Process of (1S,2R)-2-tert-butyldiphenylsilyloxy-1-methyl-3-butenyl (S)-3-hydroxybutyrate

There total 4 articles about (1S,2R)-2-tert-butyldiphenylsilyloxy-1-methyl-3-butenyl (S)-3-hydroxybutyrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 1335286-53-7
(1S,2R)-2-tert-butyldiphenylsilyloxy-1-methyl-3-butenyl (S)-3-tert-butyldimethylsilyloxybutyrate

: 1335286-54-8
(1S,2R)-2-tert-butyldiphenylsilyloxy-1-methyl-3-butenyl (S)-3-hydroxybutyrate

Guidance literature:: With water; acetic acid; In tetrahydrofuran; Inert atmosphere;
DOI:10.1016/j.tet.2011.08.014

Reference yield:

: 1135051-09-0
(2R,3S)-3-tert-butyldiphenylsilyloxy-4-penten-2-ol

: 1335286-54-8
(1S,2R)-2-tert-butyldiphenylsilyloxy-1-methyl-3-butenyl (S)-3-hydroxybutyrate

Guidance literature:: Multi-step reaction with 2 steps

1: dmap / toluene / 1 h / 20 °C / Inert atmosphere

2: water; acetic acid / tetrahydrofuran / Inert atmosphere

With dmap; water; acetic acid; In tetrahydrofuran; toluene; 1: Yamaguchi reaction;
DOI:10.1016/j.tet.2011.08.014

Reference yield:

: 1174412-62-4
(3R,4S)-4-tert-butyldimethylsilyloxy-3-tert-butyldiphenylsilyloxy-1-pentene

: 1335286-54-8
(1S,2R)-2-tert-butyldiphenylsilyloxy-1-methyl-3-butenyl (S)-3-hydroxybutyrate

Guidance literature:: Multi-step reaction with 3 steps

1: water; acetic acid / tetrahydrofuran / Inert atmosphere

2: dmap / toluene / 1 h / 20 °C / Inert atmosphere

3: water; acetic acid / tetrahydrofuran / Inert atmosphere

With dmap; water; acetic acid; In tetrahydrofuran; toluene; 2: Yamaguchi reaction;
DOI:10.1016/j.tet.2011.08.014