(+/-)-(E)-methyl 5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-enoate

Base Information

Chemical Name:(+/-)-(E)-methyl 5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-enoate
CAS No.:1263067-99-7
Molecular Formula:C₂₁H₃₄O₅Si
Molecular Weight:394.583
Hs Code.:

Synonyms:(+/-)-(E)-methyl 5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-enoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+/-)-(E)-methyl 5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-enoate

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Technology Process of (+/-)-(E)-methyl 5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-enoate

There total 1 articles about (+/-)-(E)-methyl 5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1263067-98-6
(+/-)-(E)-methyl 5-(tert-butyldimethylsilyloxy)-4-hydroxy-4-methylpent-2-enoate

: 89238-99-3
O-(4-methoxybenzyl)-trichloroacetimidate

: 1263067-99-7
(+/-)-(E)-methyl 5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-enoate

Guidance literature:: With lanthanum(lll) triflate; In toluene; at 20 ℃; for 16h; Inert atmosphere;
DOI:10.1016/j.tet.2010.10.071

Reference yield: 89.0%

: 1263067-99-7
(+/-)-(E)-methyl 5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-enoate

: 1263068-00-3
(+/-)-(E)-5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-enoic acid

Guidance literature:: (+/-)-(E)-methyl 5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-enoate; With water; lithium hydroxide; In tetrahydrofuran; at 0 - 20 ℃; for 46h;

With sodium dihydrogenphosphate; In tetrahydrofuran; water;
DOI:10.1016/j.tet.2010.10.071

Reference yield: 89.0%

: 1263067-99-7
(+/-)-(E)-methyl 5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-enoate

: 1263068-01-4
(+/-)-(E)-5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-en-1-ol

Guidance literature:: (+/-)-(E)-methyl 5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)-4-methylpent-2-enoate; With diisobutylaluminium hydride; In hexane; dichloromethane; at -78 ℃; for 3h; Inert atmosphere;

With methanol; In hexane; dichloromethane; at -78 - 20 ℃;

With water; rochelle salt; In diethyl ether; hexane; dichloromethane; at 20 ℃; for 0.25h;
DOI:10.1016/j.tet.2010.10.071