(1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-2,6,11-trioxa-tricyclo[8.5.0.0^3,7]pentadecan-5-one

Base Information

• Chemical Name: (1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-2,6,11-trioxa-tricyclo[8.5.0.0^3,7]pentadecan-5-one
• CAS No.: 908866-13-7
• Molecular Formula: C₂₇H₃₂O₆
• Molecular Weight: 452.547

Synonyms:(1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-2,6,11-trioxa-tricyclo[8.5.0.0^3,7]pentadecan-5-one

Chemical Property of (1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-2,6,11-trioxa-tricyclo[8.5.0.0^3,7]pentadecan-5-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-2,6,11-trioxa-tricyclo[8.5.0.0^3,7]pentadecan-5-one

There total 13 articles about (1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-2,6,11-trioxa-tricyclo[8.5.0.0^3,7]pentadecan-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

(E)-3-[(2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-(3-oxo-propyl)-oxepan-3-yloxy]-acrylic acid methyl ester (908866-12-6) → (1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-2,6,11-trioxa-tricyclo[8.5.0.03,7]pentadecan-5-one (908866-13-7)

Guidance literature:

(E)-3-[(2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-(3-oxo-propyl)-oxepan-3-yloxy]-acrylic acid methyl ester; With methanol; samarium diiodide; In tetrahydrofuran; at 20 ℃; for 0.5h;

With toluene-4-sulfonic acid; In toluene; at 80 ℃; for 1h;

DOI:10.1021/ja066772y

Reference yield: 74.0%

(E)-3-[(2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-(3-oxo-propyl)-oxepan-3-yloxy]-acrylic acid methyl ester (908866-12-6) → (1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-2,6,11-trioxa-tricyclo[8.5.0.03,7]pentadecan-5-one (908866-13-7) + ((2R,3S,5aR,7S,8R,10aS)-8-Benzyloxy-7-benzyloxymethyl-3-hydroxy-decahydro-1,6-dioxa-heptalen-2-yl)-acetic acid methyl ester

Guidance literature:

With methanol; samarium diiodide; In tetrahydrofuran; at 20 ℃; for 0.5h;

DOI:10.1021/ja062524q

Reference yield:

((2R,3S,5aR,7S,8R,10aS)-8-Benzyloxy-7-benzyloxymethyl-3-hydroxy-decahydro-1,6-dioxa-heptalen-2-yl)-acetic acid methyl ester → (1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-2,6,11-trioxa-tricyclo[8.5.0.03,7]pentadecan-5-one (908866-13-7)

Guidance literature:

With toluene-4-sulfonic acid; In toluene; at 80 ℃; for 1h;

DOI:10.1021/ja062524q

upstream raw materials:

(E)-3-[(2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-(3-oxo-propyl)-oxepan-3-yloxy]-acrylic acid methyl ester

((2R,4aR,6S,7R,9aS)-7-Benzyloxy-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-yl)-methanol

(2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-hydroxymethyl-oxepan-3-ol

(2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-(2-[1,3]dithian-2-yl-ethyl)-oxepan-3-ol

Downstream raw materials:

C₇₃H₁₁₄O₈SeSi₃

C₇₀H₁₂₀O₉Si₄

C₇₀H₁₁₆O₁₀Si₄

C₆₇H₁₀₈O₈Si₃

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 908866-13-7 (1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-2,6,11-trioxa-tricyclo[8.5.0.0^3,7]pentadecan-5-one

Send

Send

Metric Ton KG G Pound L ML

Send

Send