meso-5-(4-formylphenyl)-10,15,20-triphenylporphyrin

Base Information

• Chemical Name: meso-5-(4-formylphenyl)-10,15,20-triphenylporphyrin
• CAS No.: 123444-61-1
• Molecular Formula: C₄₅H₃₀N₄O
• Molecular Weight: 642.759
• Mol file: 123444-61-1.mol

Synonyms:meso-5-(4-formylphenyl)-10,15,20-triphenylporphyrin

Chemical Property of meso-5-(4-formylphenyl)-10,15,20-triphenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of meso-5-(4-formylphenyl)-10,15,20-triphenylporphyrin

There total 11 articles about meso-5-(4-formylphenyl)-10,15,20-triphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

meso-5-(4-hydroxymethylphenyl)-10,15,20-triphenylporphyrin → meso-5-(4-formylphenyl)-10,15,20-triphenylporphyrin (123444-61-1)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1021/ja209763u

Reference yield: 86.0%

5-(4-methoxycarbonylphenyl)-10,15,20-triphenyl-21H,23H-porphyrin → meso-5-(4-formylphenyl)-10,15,20-triphenylporphyrin (123444-61-1)

Guidance literature:

5-(4-methoxycarbonylphenyl)-10,15,20-triphenyl-21H,23H-porphyrin; With lithium aluminium tetrahydride; In tetrahydrofuran;

With manganese(IV) oxide; In tetrahydrofuran; dichloromethane;

DOI:10.1007/s00706-004-0276-5

Reference yield: 84.0%

5-(4-chloromethylphenyl)-10,15,20-phenyl porphyrin → 5-(p-formylphenyl)-10,15,20-triphenylporphyrin (123444-61-1)

Guidance literature:

5-(4-chloromethylphenyl)-10,15,20-phenyl porphyrin; With hexamethylenetetramine; In chloroform; at 45 ℃; for 15h;

With water; acetic acid; for 10h; Reflux;

DOI:10.1007/s11164-013-1525-1

upstream raw materials:

5-bromo-10,20-dihexyl-15-phenylporphyrin (5)

p-(1,3-Dioxolan-2-yl)iodobenzene

5-(4-bromophenyl)-10,15,20-triphenylporphyrin

N,N-dimethyl-formamide

Downstream raw materials:

C₈₂H₅₄N₈